Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate

Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate

The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P...P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The molec...

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Bibliographic Details
Main Authors: Christina Taouss, Peter G. Jones
Format: Article
Language:English
Published: International Union of Crystallography 2016-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
gold
phosphine
chalcogenide
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016009816
Description
Summary:The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P...P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The molecules associate to form broad ribbons parallel to the c axis via two C—H...O, one C—H...Cl(Au) and one Au...Cl interaction.
ISSN:2056-9890

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