Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]

Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]

In the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)]n, the CdII cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a...

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Main Authors: Shao-Gang Hou, Mei-Fang Jin
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811054183
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spelling doaj-a41b5458ae6c43ac88b08803e3417ac92020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m84m8510.1107/S1600536811054183Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]Shao-Gang HouMei-Fang JinIn the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)]n, the CdII cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal–bipyramidal geometry. Each TMIPA anion bridges three CdII cations, forming polymeric complex sheets parallel to (001). Weak C—H...O hydrogen bonding occurs between adjacent sheets.http://scripts.iucr.org/cgi-bin/paper?S1600536811054183
collection DOAJ
language English
format Article
sources DOAJ
author Shao-Gang Hou
Mei-Fang Jin
spellingShingle Shao-Gang Hou
Mei-Fang Jin
Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
Acta Crystallographica Section E
author_facet Shao-Gang Hou
Mei-Fang Jin
author_sort Shao-Gang Hou
title Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
title_short Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
title_full Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
title_fullStr Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
title_full_unstemmed Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]
title_sort poly[(2,2′-bipyridine-κ2n,n′)(μ3-2,4,6-trimethylisophthalato-κ5o1,o1′:o1:o3,o3′)cadmium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description In the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)]n, the CdII cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal–bipyramidal geometry. Each TMIPA anion bridges three CdII cations, forming polymeric complex sheets parallel to (001). Weak C—H...O hydrogen bonding occurs between adjacent sheets.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811054183
work_keys_str_mv AT shaoganghou poly22amp8242bipyridineamp9542nnamp8242amp9563246trimethylisophthalatoamp9545o1o1amp8242o1o3o3amp8242cadmium
AT meifangjin poly22amp8242bipyridineamp9542nnamp8242amp9563246trimethylisophthalatoamp9545o1o1amp8242o1o3o3amp8242cadmium
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