Double-layer buffer template to grow commensurate epitaxial BaBiO3 thin films

We propose a BaCeO3/BaZrO3 double-layer buffer template, grown on a SrTiO3 substrate, for epitaxial growth of a target oxide film with large lattice constants of over 4.1 Å. Lattice mismatch from the substrate was mostly accommodated for by a BaZrO3 arbitrating layer. Having an ideal in-plane lattic...

Full description

Bibliographic Details
Main Authors: Han Gyeol Lee, Yoonkoo Kim, Sangwoon Hwang, Gideok Kim, Tae Dong Kang, Minu Kim, Miyoung Kim, Tae Won Noh
Format: Article
Language:English
Published: AIP Publishing LLC 2016-12-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4972133
Description
Summary:We propose a BaCeO3/BaZrO3 double-layer buffer template, grown on a SrTiO3 substrate, for epitaxial growth of a target oxide film with large lattice constants of over 4.1 Å. Lattice mismatch from the substrate was mostly accommodated for by a BaZrO3 arbitrating layer. Having an ideal in-plane lattice structure, BaCeO3 served as the main-buffer to grow the target material. We demonstrated commensurate epitaxy of BaBiO3 (BBO, a = 4.371 Å) utilizing the new buffer template. Our results can be applied to heteroepitaxy and strain engineering of novel oxide materials of sizable lattice constants.
ISSN:2166-532X