[meso-5,10,15,20-Tetrakis(3-methylthiophen-2-yl)porphyrinato-κ4N,N′,N′′,N′′′]nickel(II) benzene hemisolvate

[meso-5,10,15,20-Tetrakis(3-methylthiophen-2-yl)porphyrinato-κ4N,N′,N′′,N′′′]nickel(II) benzene hemisolvate

In the title compound, [Ni(C40H28N4S4)]·0.5C6H6, the NiII atom is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N4 donor set and the pyrrole rings being in the range 16.24 (5)&...

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Bibliographic Details
Main Authors: Ray J. Butcher, Sushil K. Gupta, P. Bhavana, R. Prasath
Format: Article
Language:English
Published: International Union of Crystallography 2013-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813030468

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