N′-[(E)-1-(2-Hydroxyphenyl)ethylidene]pyrazine-2-carbohydrazide

The title compound, C13H12N4O2, crystallized with two independent molecules (A and B) in the asymmetric unit. Molecule B is planar to within 0.044 (3) Å for all non-H atoms, while molecule A is slightly twisted, with a dihedral angle of 6.29 (4)° betwe...

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Bibliographic Details
Main Authors: Shahid Hameed, Mushtaq Ahmad, M. Nawaz Tahir, Muhammad Israr, Muhammad Anwar
Format: Article
Language:English
Published: International Union of Crystallography 2013-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813022137
Description
Summary:The title compound, C13H12N4O2, crystallized with two independent molecules (A and B) in the asymmetric unit. Molecule B is planar to within 0.044 (3) Å for all non-H atoms, while molecule A is slightly twisted, with a dihedral angle of 6.29 (4)° between the mean planes of the pyrazine-2-carbohydrazide and 1-(2-hydroxyphenyl)ethanone moieties (r.m.s. deviations = 0.0348 and 0.0428 Å, respectively). S(5) and S(6) ring motifs are formed in both molecules due to the presence of intramolecular O—H...N and N—H...N hydrogen bonds. In the crystal, molecules A and B are linked by a C—H...O hydrogen bond. They stack along the a-axis direction, forming columns with π–π interactions involving inversion-related pyrazine and benzene rings [centroid–centroid distances = 3.5489 (13)–3.8513 (16) Å].
ISSN:1600-5368