Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique

Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique

In this work, substantial evidence was obtained for ligand reduction in cerium tetrakis acac complexes. Also, this ligand reduction of a negatively charged ligand proved to depend far less on the nature central metal than neutral ligands does. It is supposed that in Mz(acac)z complexes the charge is...

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Main Author: Baghdad Science Journal
Format: Article
Language:Arabic
Published: College of Science for Women, University of Baghdad 2008-06-01
Series:Baghdad Science Journal
Online Access:http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/898
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spelling doaj-a38b374b107042b5a4e3a49df9333ed22020-11-25T01:39:50ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862008-06-015210.21123/bsj.5.2.278-284Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry techniqueBaghdad Science JournalIn this work, substantial evidence was obtained for ligand reduction in cerium tetrakis acac complexes. Also, this ligand reduction of a negatively charged ligand proved to depend far less on the nature central metal than neutral ligands does. It is supposed that in Mz(acac)z complexes the charge is distributed evenly over the whole molecule. In this work these complexes were prepared and characterized by IR and CHN analysis to indicate the purities of these complexes. The electrochemistry techniques were shown as obtained for ligand reduction. This research was carried out at School of Chemistry and Molecular Science, Sussex University, U.K.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/898
collection DOAJ
language Arabic
format Article
sources DOAJ
author Baghdad Science Journal
spellingShingle Baghdad Science Journal
Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique
Baghdad Science Journal
author_facet Baghdad Science Journal
author_sort Baghdad Science Journal
title Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique
title_short Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique
title_full Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique
title_fullStr Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique
title_full_unstemmed Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique
title_sort ligand reduction in variously substituted cerium (iv) tetrakis acetylacetone complexes by electrochemistry technique
publisher College of Science for Women, University of Baghdad
series Baghdad Science Journal
issn 2078-8665
2411-7986
publishDate 2008-06-01
description In this work, substantial evidence was obtained for ligand reduction in cerium tetrakis acac complexes. Also, this ligand reduction of a negatively charged ligand proved to depend far less on the nature central metal than neutral ligands does. It is supposed that in Mz(acac)z complexes the charge is distributed evenly over the whole molecule. In this work these complexes were prepared and characterized by IR and CHN analysis to indicate the purities of these complexes. The electrochemistry techniques were shown as obtained for ligand reduction. This research was carried out at School of Chemistry and Molecular Science, Sussex University, U.K.
url http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/898
work_keys_str_mv AT baghdadsciencejournal ligandreductioninvariouslysubstitutedceriumivtetrakisacetylacetonecomplexesbyelectrochemistrytechnique
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