Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV)
In the title molecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N—H...Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of al...
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International Union of Crystallography
2020-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S205698902000941X |
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doaj-a384cc631b004e65821feba1df0adc422020-11-25T03:44:45ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-08-017681279128310.1107/S205698902000941Xhb7922Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV)Rochdi Ghallab0Mehdi Boutebdja1George Dénès2Hocine Merazig3Environmental Molecular, and Structural Chemistry Research Unit, University of, Constantine-1, 25000, Constantine, AlgeriaEnvironmental Molecular, and Structural Chemistry Research Unit, University of, Constantine-1, 25000, Constantine, AlgeriaLaboratory of Solid State Chemistry and Mossbauer Spectroscopy, Departement of, Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St. West, Montreal, H4B 1R6, QC, CanadaEnvironmental Molecular, and Structural Chemistry Research Unit, University of, Constantine-1, 25000, Constantine, AlgeriaIn the title molecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N—H...Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the intermolecular interactions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.http://scripts.iucr.org/cgi-bin/paper?S205698902000941Xzero-dimensional hybrid perovskiteaminopyridinehirshfeld surfaceraman spectroscopycrystal structure |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Rochdi Ghallab Mehdi Boutebdja George Dénès Hocine Merazig |
| spellingShingle |
Rochdi Ghallab Mehdi Boutebdja George Dénès Hocine Merazig Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV) Acta Crystallographica Section E: Crystallographic Communications zero-dimensional hybrid perovskite aminopyridine hirshfeld surface raman spectroscopy crystal structure |
| author_facet |
Rochdi Ghallab Mehdi Boutebdja George Dénès Hocine Merazig |
| author_sort |
Rochdi Ghallab |
| title |
Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV) |
| title_short |
Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV) |
| title_full |
Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV) |
| title_fullStr |
Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV) |
| title_full_unstemmed |
Synthesis, crystal structure and Hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(IV) |
| title_sort |
synthesis, crystal structure and hirshfeld surface of bis(2-aminopyridinium) hexachloridostannate(iv) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E: Crystallographic Communications |
| issn |
2056-9890 |
| publishDate |
2020-08-01 |
| description |
In the title molecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N—H...Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the intermolecular interactions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported. |
| topic |
zero-dimensional hybrid perovskite aminopyridine hirshfeld surface raman spectroscopy crystal structure |
| url |
http://scripts.iucr.org/cgi-bin/paper?S205698902000941X |
| work_keys_str_mv |
AT rochdighallab synthesiscrystalstructureandhirshfeldsurfaceofbis2aminopyridiniumhexachloridostannateiv AT mehdiboutebdja synthesiscrystalstructureandhirshfeldsurfaceofbis2aminopyridiniumhexachloridostannateiv AT georgedenes synthesiscrystalstructureandhirshfeldsurfaceofbis2aminopyridiniumhexachloridostannateiv AT hocinemerazig synthesiscrystalstructureandhirshfeldsurfaceofbis2aminopyridiniumhexachloridostannateiv |
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