(2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)

In the title complex, [Ni(C15H11ClN2O3)(C3H4N2)], the NiII ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole molecule, forming a distorted square-planar geometry. Intermolecular N—H...N hydrogen bonds link nei...

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Main Author: Xiao-Hua Chen
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808028171
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spelling doaj-a3019c2f6302493c8d73da78af3016a22020-11-24T21:51:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1253m125310.1107/S1600536808028171(2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)Xiao-Hua ChenIn the title complex, [Ni(C15H11ClN2O3)(C3H4N2)], the NiII ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole molecule, forming a distorted square-planar geometry. Intermolecular N—H...N hydrogen bonds link neighboring molecules into extended chains parallel to [100].http://scripts.iucr.org/cgi-bin/paper?S1600536808028171
collection DOAJ
language English
format Article
sources DOAJ
author Xiao-Hua Chen
spellingShingle Xiao-Hua Chen
(2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)
Acta Crystallographica Section E
author_facet Xiao-Hua Chen
author_sort Xiao-Hua Chen
title (2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)
title_short (2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)
title_full (2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)
title_fullStr (2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)
title_full_unstemmed (2-{[2-(4-Chlorophenoxy)-1-oxidoethylidene-κO1]hydrazonomethyl}phenolato-κ2N1,O)(1H-imidazole-κN3)nickel(II)
title_sort (2-{[2-(4-chlorophenoxy)-1-oxidoethylidene-κo1]hydrazonomethyl}phenolato-κ2n1,o)(1h-imidazole-κn3)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-10-01
description In the title complex, [Ni(C15H11ClN2O3)(C3H4N2)], the NiII ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole molecule, forming a distorted square-planar geometry. Intermolecular N—H...N hydrogen bonds link neighboring molecules into extended chains parallel to [100].
url http://scripts.iucr.org/cgi-bin/paper?S1600536808028171
work_keys_str_mv AT xiaohuachen 224chlorophenoxy1oxidoethylidene954o1hydrazonomethylphenolato9542n1o1himidazole954n3nickelii
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