trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)

trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)

In the title compound, [Mn(NO3)2(C12H8N2)2], the MnII atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N4O2 octahedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a tw...

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Main Authors: Watcharin Saphu, Songwuit Chanthee, Kittipong Chainok, David J. Harding, Chaveng Pakawatchai
Format: Article
Language:English
Published: International Union of Crystallography 2012-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812029364
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spelling doaj-a2f8d48e8cb04c518499cb9aa196b7b32020-11-24T22:08:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688m1026m102610.1107/S1600536812029364trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)Watcharin SaphuSongwuit ChantheeKittipong ChainokDavid J. HardingChaveng PakawatchaiIn the title compound, [Mn(NO3)2(C12H8N2)2], the MnII atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N4O2 octahedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, molecules are linked by weak C—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 4.088 (5) Å] into a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536812029364
collection DOAJ
language English
format Article
sources DOAJ
author Watcharin Saphu
Songwuit Chanthee
Kittipong Chainok
David J. Harding
Chaveng Pakawatchai
spellingShingle Watcharin Saphu
Songwuit Chanthee
Kittipong Chainok
David J. Harding
Chaveng Pakawatchai
trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
Acta Crystallographica Section E
author_facet Watcharin Saphu
Songwuit Chanthee
Kittipong Chainok
David J. Harding
Chaveng Pakawatchai
author_sort Watcharin Saphu
title trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
title_short trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
title_full trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
title_fullStr trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
title_full_unstemmed trans-Bis(nitrato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)
title_sort trans-bis(nitrato-κo)bis(1,10-phenanthroline-κ2n,n′)manganese(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-08-01
description In the title compound, [Mn(NO3)2(C12H8N2)2], the MnII atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N4O2 octahedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, molecules are linked by weak C—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 4.088 (5) Å] into a three-dimensional supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812029364
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AT songwuitchanthee transbisnitratoamp954obis110phenanthrolineamp9542nnamp8242manganeseii
AT kittipongchainok transbisnitratoamp954obis110phenanthrolineamp9542nnamp8242manganeseii
AT davidjharding transbisnitratoamp954obis110phenanthrolineamp9542nnamp8242manganeseii
AT chavengpakawatchai transbisnitratoamp954obis110phenanthrolineamp9542nnamp8242manganeseii
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