Influence of the stationary and mobile phase composition on solvent strength parameter εº and SP system parameter in NP column chromatography
It is shown that SP system parameters, previously used for the linearization of log k values in RP chromatography, can also be used in NP chromatography. Avery good linear correlation between SP parameter and the earlier described Snyder solvent strength parameter has been established. It was also f...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Serbian Chemical Society
2002-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2002/0352-51390207481J.pdf |
| Summary: | It is shown that SP system parameters, previously used for the linearization of log k values in RP chromatography, can also be used in NP chromatography. Avery good linear correlation between SP parameter and the earlier described Snyder solvent strength parameter has been established. It was also found that the phase equilibrium constant K is independent of the polarity and concentration of the more polar component of binary solvent mixtures. |
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| ISSN: | 0352-5139 1820-7421 |