Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)

Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)

In the title compound, [CoIICl2(C6H10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl− anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit ar...

Full description

Bibliographic Details
Main Authors: Ganna Lyubartseva, Sean Parkin
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681003254X
id doaj-a213d4ae85fa46e9aeb1a54c3f71bb9f
record_format Article
spelling doaj-a213d4ae85fa46e9aeb1a54c3f71bb9f2020-11-25T01:13:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1134m113410.1107/S160053681003254XDichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)Ganna LyubartsevaSean ParkinIn the title compound, [CoIICl2(C6H10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl− anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N—H...Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis. http://scripts.iucr.org/cgi-bin/paper?S160053681003254X
collection DOAJ
language English
format Article
sources DOAJ
author Ganna Lyubartseva
Sean Parkin
spellingShingle Ganna Lyubartseva
Sean Parkin
Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
Acta Crystallographica Section E
author_facet Ganna Lyubartseva
Sean Parkin
author_sort Ganna Lyubartseva
title Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
title_short Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
title_full Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
title_fullStr Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
title_full_unstemmed Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
title_sort dichloridobis(3,4,5-trimethyl-1h-pyrazole-κn2)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description In the title compound, [CoIICl2(C6H10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl− anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N—H...Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis.
url http://scripts.iucr.org/cgi-bin/paper?S160053681003254X
work_keys_str_mv AT gannalyubartseva dichloridobis345trimethyl1hpyrazoleamp954n2cobaltii
AT seanparkin dichloridobis345trimethyl1hpyrazoleamp954n2cobaltii
_version_ 1725161690933231616

Similar Items