Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN2)cobalt(II)
In the title compound, [CoIICl2(C6H10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl− anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit ar...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681003254X |
| Summary: | In the title compound, [CoIICl2(C6H10N2)2], a pair of 3,4,5-trimethylpyrazoles act as monodentate ligands. Two Cl− anions are also bonded directly to the CoII atom, which has a CoN2Cl2 chromophore in a slightly distorted tetrahedral geometry. The two molecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N—H...Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis. |
|---|---|
| ISSN: | 1600-5368 |