Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)

The title compound, [Sn4(C8H17)8O2(C6H5N2O2)4], is a tetranuclear SnIV complex, built up by inversion symmetry around the central Sn2O2 ring. The SnIV coordination geometries are distorted SnO3C2 trigonal-bipyramidal and distorted SnO4C2 octahedral. The three-coordinate &#956;3-oxido bridgin...

Full description

Bibliographic Details
Main Authors:	Fahui Li, Zhongjun Gao
Format:	Article
Language:	English
Published:	International Union of Crystallography 2009-12-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536809047345

id	doaj-a1fe51decd854cf0a00043d514c9d486
record_format	Article
spelling	doaj-a1fe51decd854cf0a00043d514c9d4862020-11-24T21:51:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1579m157910.1107/S1600536809047345Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)Fahui LiZhongjun GaoThe title compound, [Sn4(C8H17)8O2(C6H5N2O2)4], is a tetranuclear SnIV complex, built up by inversion symmetry around the central Sn2O2 ring. The SnIV coordination geometries are distorted SnO3C2 trigonal-bipyramidal and distorted SnO4C2 octahedral. The three-coordinate &#956;3-oxido bridging O atom in the Sn2O2 ring is attached to three Sn atoms. All non-H atoms, with the exception of the Sn-bonded octyl groups, lie approximately on a non-crystallographic mirror plane. http://scripts.iucr.org/cgi-bin/paper?S1600536809047345
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Fahui Li Zhongjun Gao
spellingShingle	Fahui Li Zhongjun Gao Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV) Acta Crystallographica Section E
author_facet	Fahui Li Zhongjun Gao
author_sort	Fahui Li
title	Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)
title_short	Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)
title_full	Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)
title_fullStr	Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)
title_full_unstemmed	Tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3N1,O:O;2:3&#954;3O:N1,O;1:2&#954;2O:O&#8242;;3:4&#954;2O:O&#8242;-octaoctyl-1&#954;2C,2&#954;2C,3&#954;2C,4&#954;2C-di-&#956;3-oxido-1:2:3&#954;3O;1:3:4&#954;3O-tetratin(IV)
title_sort	tetrakis(&#956;2-5-methylpyrazine-2-carboxylato)-1:2&#954;3n1,o:o;2:3&#954;3o:n1,o;1:2&#954;2o:o&#8242;;3:4&#954;2o:o&#8242;-octaoctyl-1&#954;2c,2&#954;2c,3&#954;2c,4&#954;2c-di-&#956;3-oxido-1:2:3&#954;3o;1:3:4&#954;3o-tetratin(iv)
publisher	International Union of Crystallography
series	Acta Crystallographica Section E
issn	1600-5368
publishDate	2009-12-01
description	The title compound, [Sn4(C8H17)8O2(C6H5N2O2)4], is a tetranuclear SnIV complex, built up by inversion symmetry around the central Sn2O2 ring. The SnIV coordination geometries are distorted SnO3C2 trigonal-bipyramidal and distorted SnO4C2 octahedral. The three-coordinate &#956;3-oxido bridging O atom in the Sn2O2 ring is attached to three Sn atoms. All non-H atoms, with the exception of the Sn-bonded octyl groups, lie approximately on a non-crystallographic mirror plane.
url	http://scripts.iucr.org/cgi-bin/paper?S1600536809047345
work_keys_str_mv	AT fahuili tetrakisamp95625methylpyrazine2carboxylato12amp9543n1oo23amp9543on1o12amp9542ooamp824234amp9542ooamp8242octaoctyl1amp9542c2amp9542c3amp9542c4amp9542cdiamp9563oxido123amp9543o134amp9543otetratiniv AT zhongjungao tetrakisamp95625methylpyrazine2carboxylato12amp9543n1oo23amp9543on1o12amp9542ooamp824234amp9542ooamp8242octaoctyl1amp9542c2amp9542c3amp9542c4amp9542cdiamp9563oxido123amp9543o134amp9543otetratiniv
_version_	1725878975280971776

Tetrakis(&amp;#956;2-5-methylpyrazine-2-carboxylato)-1:2&amp;#954;3N1,O:O;2:3&amp;#954;3O:N1,O;1:2&amp;#954;2O:O&amp;#8242;;3:4&amp;#954;2O:O&amp;#8242;-octaoctyl-1&amp;#954;2C,2&amp;#954;2C,3&amp;#954;2C,4&amp;#954;2C-di-&amp;#956;3-oxido-1:2:3&amp;#954;3O;1:3:4&amp;#954;3O-tetratin(IV)

Similar Items

Tetrakis(μ2-5-methylpyrazine-2-carboxylato)-1:2κ3N1,O:O;2:3κ3O:N1,O;1:2κ2O:O′;3:4κ2O:O′-octaoctyl-1κ2C,2κ2C,3κ2C,4κ2C-di-μ3-oxido-1:2:3κ3O;1:3:4κ3O-tetratin(IV)