Tetrakis(μ2-5-methylpyrazine-2-carboxylato)-1:2κ3N1,O:O;2:3κ3O:N1,O;1:2κ2O:O′;3:4κ2O:O′-octaoctyl-1κ2C,2κ2C,3κ2C,4κ2C-di-μ3-oxido-1:2:3κ3O;1:3:4κ3O-tetratin(IV)
The title compound, [Sn4(C8H17)8O2(C6H5N2O2)4], is a tetranuclear SnIV complex, built up by inversion symmetry around the central Sn2O2 ring. The SnIV coordination geometries are distorted SnO3C2 trigonal-bipyramidal and distorted SnO4C2 octahedral. The three-coordinate μ3-oxido bridgin...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809047345 |
| Summary: | The title compound, [Sn4(C8H17)8O2(C6H5N2O2)4], is a tetranuclear SnIV complex, built up by inversion symmetry around the central Sn2O2 ring. The SnIV coordination geometries are distorted SnO3C2 trigonal-bipyramidal and distorted SnO4C2 octahedral. The three-coordinate μ3-oxido bridging O atom in the Sn2O2 ring is attached to three Sn atoms. All non-H atoms, with the exception of the Sn-bonded octyl groups, lie approximately on a non-crystallographic mirror plane. |
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| ISSN: | 1600-5368 |