(N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)

(N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)

In the title compound, [ZnBr3(C4H12N5)], the ZnII cation is tetrahedrally coordinated by three bromide ions and the (N-{amino[(diaminomethylene)amino]methylene}-N-methylmethanaminium) cation that binds through the central N atom. The complex is of interest as a potential antidiabetic drug of the big...

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Main Authors: Juan M. Germán-Acacio, Chrystian Rivas Arzate, Zeus Cardenas-Valencia, Marcos Flores-Alamo, David Morales-Morales
Format: Article
Language:English
Published: International Union of Crystallography 2016-06-01
Series:IUCrData
Subjects:
crystal
structure MetforminH+
zinc-complex
hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616008555
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spelling doaj-a1ed431a30ce4173a7c5c8376ba317cd2020-11-24T23:10:05ZengInternational Union of CrystallographyIUCrData2414-31462016-06-0116x16085510.1107/S2414314616008555sj4040(N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)Juan M. Germán-Acacio0Chrystian Rivas Arzate1Zeus Cardenas-Valencia2Marcos Flores-Alamo3David Morales-Morales4Research Support Network, Instituto Nacional de Ciencias Médicas y Nutrición SZ-Universidad Nacional Autónoma de México (CIC-UNAM), México D.F. MexicoResearch Support Network, Instituto Nacional de Ciencias Médicas y Nutrición SZ-Universidad Nacional Autónoma de México (CIC-UNAM), México D.F. MexicoResearch Support Network, Instituto Nacional de Ciencias Médicas y Nutrición SZ-Universidad Nacional Autónoma de México (CIC-UNAM), México D.F. MexicoFacultad de Química, Universidad, Nacional Autónoma de México, CDMX 04510, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, CDMX 04510, MexicoIn the title compound, [ZnBr3(C4H12N5)], the ZnII cation is tetrahedrally coordinated by three bromide ions and the (N-{amino[(diaminomethylene)amino]methylene}-N-methylmethanaminium) cation that binds through the central N atom. The complex is of interest as a potential antidiabetic drug of the biguanide family. The crystal structure is stabilized by an extensive series of N—H...Br and C—H...Br hydrogen bonds, which combine to form a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S2414314616008555crystalstructure MetforminH+zinc-complexhydrogen bonds
collection DOAJ
language English
format Article
sources DOAJ
author Juan M. Germán-Acacio
Chrystian Rivas Arzate
Zeus Cardenas-Valencia
Marcos Flores-Alamo
David Morales-Morales
spellingShingle Juan M. Germán-Acacio
Chrystian Rivas Arzate
Zeus Cardenas-Valencia
Marcos Flores-Alamo
David Morales-Morales
(N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)
IUCrData
crystal
structure MetforminH+
zinc-complex
hydrogen bonds
author_facet Juan M. Germán-Acacio
Chrystian Rivas Arzate
Zeus Cardenas-Valencia
Marcos Flores-Alamo
David Morales-Morales
author_sort Juan M. Germán-Acacio
title (N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)
title_short (N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)
title_full (N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)
title_fullStr (N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)
title_full_unstemmed (N-{Amino[(diaminomethylidene)amino]methylidene}-N-methylmethanaminium)tribromidozinc(II)
title_sort (n-{amino[(diaminomethylidene)amino]methylidene}-n-methylmethanaminium)tribromidozinc(ii)
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-06-01
description In the title compound, [ZnBr3(C4H12N5)], the ZnII cation is tetrahedrally coordinated by three bromide ions and the (N-{amino[(diaminomethylene)amino]methylene}-N-methylmethanaminium) cation that binds through the central N atom. The complex is of interest as a potential antidiabetic drug of the biguanide family. The crystal structure is stabilized by an extensive series of N—H...Br and C—H...Br hydrogen bonds, which combine to form a three-dimensional structure.
topic crystal
structure MetforminH+
zinc-complex
hydrogen bonds
url http://scripts.iucr.org/cgi-bin/paper?S2414314616008555
work_keys_str_mv AT juanmgermanacacio naminodiaminomethylideneaminomethylidenenmethylmethanaminiumtribromidozincii
AT chrystianrivasarzate naminodiaminomethylideneaminomethylidenenmethylmethanaminiumtribromidozincii
AT zeuscardenasvalencia naminodiaminomethylideneaminomethylidenenmethylmethanaminiumtribromidozincii
AT marcosfloresalamo naminodiaminomethylideneaminomethylidenenmethylmethanaminiumtribromidozincii
AT davidmoralesmorales naminodiaminomethylideneaminomethylidenenmethylmethanaminiumtribromidozincii
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