(N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)

(N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)

The title compound, [Sn(C6H5)3(C9H10NS2)], has two independent molecules in the asymmetric unit and each features a tetrahedrally coordinated SnIV atom as the dithiocarbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn...S(thione...

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Main Authors: Nurul Farahana Kamaludin, Ibrahim Baba, Normah Awang, Mohamed Ibrahim Mohamed Tahir, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053591
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spelling doaj-a1db9c28539a4925b29a7db6da3d7a1d2020-11-25T01:52:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m62m6310.1107/S1600536811053591(N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)Nurul Farahana KamaludinIbrahim BabaNormah AwangMohamed Ibrahim Mohamed TahirEdward R. T. TiekinkThe title compound, [Sn(C6H5)3(C9H10NS2)], has two independent molecules in the asymmetric unit and each features a tetrahedrally coordinated SnIV atom as the dithiocarbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn...S(thione) = 3.1477 (6) and 2.9970 (5) Å for the independent molecules], distortions from the ideal geometry are evident [the widest angle being 120.48 (5)°]. The most notable feature of the crystal packing is the formation of C—H...π interactions that lead to the formation of supramolecular layers parallel to (overline{3}2overline{1}).http://scripts.iucr.org/cgi-bin/paper?S1600536811053591
collection DOAJ
language English
format Article
sources DOAJ
author Nurul Farahana Kamaludin
Ibrahim Baba
Normah Awang
Mohamed Ibrahim Mohamed Tahir
Edward R. T. Tiekink
spellingShingle Nurul Farahana Kamaludin
Ibrahim Baba
Normah Awang
Mohamed Ibrahim Mohamed Tahir
Edward R. T. Tiekink
(N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
Acta Crystallographica Section E
author_facet Nurul Farahana Kamaludin
Ibrahim Baba
Normah Awang
Mohamed Ibrahim Mohamed Tahir
Edward R. T. Tiekink
author_sort Nurul Farahana Kamaludin
title (N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
title_short (N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
title_full (N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
title_fullStr (N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
title_full_unstemmed (N-Ethyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
title_sort (n-ethyl-n-phenyldithiocarbamato-κs)triphenyltin(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description The title compound, [Sn(C6H5)3(C9H10NS2)], has two independent molecules in the asymmetric unit and each features a tetrahedrally coordinated SnIV atom as the dithiocarbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn...S(thione) = 3.1477 (6) and 2.9970 (5) Å for the independent molecules], distortions from the ideal geometry are evident [the widest angle being 120.48 (5)°]. The most notable feature of the crystal packing is the formation of C—H...π interactions that lead to the formation of supramolecular layers parallel to (overline{3}2overline{1}).
url http://scripts.iucr.org/cgi-bin/paper?S1600536811053591
work_keys_str_mv AT nurulfarahanakamaludin nethylnphenyldithiocarbamatoamp954striphenyltiniv
AT ibrahimbaba nethylnphenyldithiocarbamatoamp954striphenyltiniv
AT normahawang nethylnphenyldithiocarbamatoamp954striphenyltiniv
AT mohamedibrahimmohamedtahir nethylnphenyldithiocarbamatoamp954striphenyltiniv
AT edwardrttiekink nethylnphenyldithiocarbamatoamp954striphenyltiniv
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