NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY

Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordina...

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Main Authors:	BASSENE SEYDOU, SEMBENE BOYE MOUHAMADOU, SIDIBE MAMADOU, DIOP LIBASSE
Format:	Article
Language:	English
Published:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2020-01-01
Series:	Journal of Engineering Studies and Research
Subjects:	bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments
Online Access:	http://jesr.ub.ro/1/article/view/2

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spelling	doaj-a1cdb85f171c49b5a03e57612943845c2021-10-05T15:53:45ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322020-01-01261NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDYBASSENE SEYDOU0SEMBENE BOYE MOUHAMADOU1SIDIBE MAMADOU2DIOP LIBASSE3Department of Chemistry, Faculty of Science and Technology, Laboratory of Mineral and Analytical Chemistry, University Cheikh Anta DIOP, Dakar, SenegalDepartment of Physics Chemistry, Faculty of Sciences and Technology of Education and Training, University Cheikh Anta Diop, Boulevard Habib Bourguiba BP 5036 Fann-Dakar, SenegalDepartment of Chemistry, Faculty of Science and Technology, Laboratory of Mineral and Analytical Chemistry, University Cheikh Anta DIOP, Dakar, SenegalDepartment of Chemistry, Faculty of Science and Technology, Laboratory of Mineral and Analytical Chemistry, University Cheikh Anta DIOP, Dakar, Senegal Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions. http://jesr.ub.ro/1/article/view/2bridging aniondiscrete or two metallic components structureselectrostatic interactionsoctahedral or trigonal bipyramidal environments
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE
spellingShingle	BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY Journal of Engineering Studies and Research bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments
author_facet	BASSENE SEYDOU SEMBENE BOYE MOUHAMADOU SIDIBE MAMADOU DIOP LIBASSE
author_sort	BASSENE SEYDOU
title	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_short	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_full	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_fullStr	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_full_unstemmed	NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY
title_sort	new phosphinato organo- and halotin(iv) derivatives, adducts and complexes: synthesis and spectroscopic study
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
series	Journal of Engineering Studies and Research
issn	2068-7559 2344-4932
publishDate	2020-01-01
description	Five new phosphinato derivatives, adducts and complexes have been synthesized and characterized by infrared and Mössbauer spectroscopies. Based on their spectroscopic data discrete or infinite chain structures are proposed, the phosphinate ion behaving as a bicoordinating bridging or a monocoordinating ligand, the environments around the tin (IV) centers being octahedral or trigonal bipyramidal. In Me4N(SnPh2)2(H2PO2)2Cl3 and Cl2Sn(H2PO2)2NMe4H2PO2, the cation is involved in electrostatic interactions with the anions.
topic	bridging anion discrete or two metallic components structures electrostatic interactions octahedral or trigonal bipyramidal environments
url	http://jesr.ub.ro/1/article/view/2
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NEW PHOSPHINATO ORGANO- AND HALOTIN(IV) DERIVATIVES, ADDUCTS AND COMPLEXES: SYNTHESIS AND SPECTROSCOPIC STUDY

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