Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact

We report an investigation of the effects of different metal systems and surface treatment on the contact performance of GaN lasers. We found that multi-element metal alloy and surface chemical treatment are the keys to achieve good ohmic behavior contacts on GaN laser diodes. Pd/Ni/Au contact demon...

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Main Authors: Wenjie Wang, Wuze Xie, Zejia Deng, Haojun Yang, Mingle Liao, Junze Li, Xiaojia Luo, Song Sun, Degang Zhao
Format: Article
Language:English
Published: MDPI AG 2019-04-01
Series:Coatings
Subjects:
GaN
Online Access:https://www.mdpi.com/2079-6412/9/5/291
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spelling doaj-a0ad263e96d941a6968b90609dc3b9d92020-11-24T21:49:00ZengMDPI AGCoatings2079-64122019-04-019529110.3390/coatings9050291coatings9050291Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic ContactWenjie Wang0Wuze Xie1Zejia Deng2Haojun Yang3Mingle Liao4Junze Li5Xiaojia Luo6Song Sun7Degang Zhao8Microsystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaMicrosystem &amp; Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, ChinaState Key Laboratory of Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Science, Beijing 100083, ChinaWe report an investigation of the effects of different metal systems and surface treatment on the contact performance of GaN lasers. We found that multi-element metal alloy and surface chemical treatment are the keys to achieve good ohmic behavior contacts on GaN laser diodes. Pd/Ni/Au contact demonstrates excellent thermal stability and lowest specific contact resistivity in these metal systems. Properly adjusting the thickness of the Pd and Ni layer and pretreating with the KOH solution can further improve the ohmic contact performance. The improved ohmic behavior of the KOH solution pretreated Pd/Ni/Au contact is attributed to removing surface oxides and the reduction of the schottky barrier heights due to the metal Pd has a high work function and the interfacial reactions occurring between the Pd, Ni, Au, and GaN extends into the GaN film. As a result, a low contact resistivity of 1.66 &#215; 10<sup>&#8722;5</sup> &#937;&#183;cm<sup>2</sup> can be achieved from Pd(10 nm)/Ni(10 nm)/Au(30 nm) contacts with KOH solution pretreated on top of the laser diode structure. The power of the GaN based laser diode with the Pd/Ni/Au metallization ohmic contact can be enhanced by 1.95 times and the threshold current decreased by 37% compared to that of the conventional ohmic contact Ni/Au.https://www.mdpi.com/2079-6412/9/5/291GaNlaser diodeohmic contactPVD depositionalloysPd/Ni/Au
collection DOAJ
language English
format Article
sources DOAJ
author Wenjie Wang
Wuze Xie
Zejia Deng
Haojun Yang
Mingle Liao
Junze Li
Xiaojia Luo
Song Sun
Degang Zhao
spellingShingle Wenjie Wang
Wuze Xie
Zejia Deng
Haojun Yang
Mingle Liao
Junze Li
Xiaojia Luo
Song Sun
Degang Zhao
Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact
Coatings
GaN
laser diode
ohmic contact
PVD deposition
alloys
Pd/Ni/Au
author_facet Wenjie Wang
Wuze Xie
Zejia Deng
Haojun Yang
Mingle Liao
Junze Li
Xiaojia Luo
Song Sun
Degang Zhao
author_sort Wenjie Wang
title Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact
title_short Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact
title_full Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact
title_fullStr Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact
title_full_unstemmed Performance Improvement of GaN Based Laser Diode Using Pd/Ni/Au Metallization Ohmic Contact
title_sort performance improvement of gan based laser diode using pd/ni/au metallization ohmic contact
publisher MDPI AG
series Coatings
issn 2079-6412
publishDate 2019-04-01
description We report an investigation of the effects of different metal systems and surface treatment on the contact performance of GaN lasers. We found that multi-element metal alloy and surface chemical treatment are the keys to achieve good ohmic behavior contacts on GaN laser diodes. Pd/Ni/Au contact demonstrates excellent thermal stability and lowest specific contact resistivity in these metal systems. Properly adjusting the thickness of the Pd and Ni layer and pretreating with the KOH solution can further improve the ohmic contact performance. The improved ohmic behavior of the KOH solution pretreated Pd/Ni/Au contact is attributed to removing surface oxides and the reduction of the schottky barrier heights due to the metal Pd has a high work function and the interfacial reactions occurring between the Pd, Ni, Au, and GaN extends into the GaN film. As a result, a low contact resistivity of 1.66 &#215; 10<sup>&#8722;5</sup> &#937;&#183;cm<sup>2</sup> can be achieved from Pd(10 nm)/Ni(10 nm)/Au(30 nm) contacts with KOH solution pretreated on top of the laser diode structure. The power of the GaN based laser diode with the Pd/Ni/Au metallization ohmic contact can be enhanced by 1.95 times and the threshold current decreased by 37% compared to that of the conventional ohmic contact Ni/Au.
topic GaN
laser diode
ohmic contact
PVD deposition
alloys
Pd/Ni/Au
url https://www.mdpi.com/2079-6412/9/5/291
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