Processing of hydroxyapatite obtained by combustion synthesis

• Main Authors: M. Canillas, R. Rivero, R. García-Carrodeguas, F. Barba, Miguel A. Rodríguez
• Format: Article
• Language: English
• Published: Elsevier 2017-09-01
• Series: Boletín de la Sociedad Española de Cerámica y Vidrio
• Subjects: Hydroxyapatite; Solution combustion synthesis; Rate controlled sintering; Weibull modulus
• Online Access: http://www.sciencedirect.com/science/article/pii/S0366317517300456

One of the reasons of implants failure are the stress forces appearing in the material–tissue interface due to the differences between their mechanical properties. For this reason, similar mechanical properties to the surrounding tissue are desirable. The synthesis of hydroxyapatite by solution combustion method and its processing have been studied in order to obtain fully dense ceramic bodies with improved mechanical strength. Combustion synthesis provides nanostructured powders characterized by a high surface area to facilitate the following sintering. Moreover, synthesis was conducted in aqueous and oxidizing media. Oxidizing media improve homogenization and increase the energy released during combustion. It gives rise to particles whose morphology and size suggest lower surface energies compared with aqueous media. The obtained powders were sintered by using a controlled sintering rate schedule. Lower surfaces energies minimize the shrinkage during sintering and relative densities measurements and diametral compression test confirm improved densification and consequently mechanical properties.