Crystal structure of bis(3-bromomesityl)(quinolin-1-ium-8-yl)boron(III) tribromide

Crystal structure of bis(3-bromomesityl)(quinolin-1-ium-8-yl)boron(III) tribromide

The title compound, C27H26.82BBr2.18N+·Br3−, is a cationic triarylborane isolated as its tribromide salt. The aryl substituents include a protonated 8-quinolyl group and two 3-bromomesityl groups. The molecule was prepared on combination of 3:1 Br2 and dimesityl(quinolin-8-yl)borane in hexanes. The...

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Bibliographic Details
Main Authors: Jungho Son, Sem Raj Tamang, James D. Hoefelmeyer
Format: Article
Language:English
Published: International Union of Crystallography 2015-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
frustrated Lewis pair
halogen
heterolysis
electrophilic aromatic substitution
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015015467

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http://scripts.iucr.org/cgi-bin/paper?S2056989015015467

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