Effect of Transition Metal Substitution on the Charge-Transfer Phase Transition and Ferromagnetism of Dithiooxalato-Bridged Hetero Metal Complexes, (<i>n</i>-C<sub>3</sub>H<sub>7</sub>)<sub>4</sub>N[Fe<sup>II</sup><sub>1−<i>x</i></sub>Mn<sup>II</sup><i><sub>x</sub></i>Fe<sup>III</sup>(dto)<sub>3</sub>]

Effect of Transition Metal Substitution on the Charge-Transfer Phase Transition and Ferromagnetism of Dithiooxalato-Bridged Hetero Metal Complexes, (<i>n</i>-C<sub>3</sub>H<sub>7</sub>)<sub>4</sub>N[Fe<sup>II</sup><sub>1−<i>x</i></sub>Mn<sup>II</sup><i><sub>x</sub></i>Fe<sup>III</sup>(dto)<sub>3</sub>]

The dithiooxalato-bridged iron mixed-valence complex (<i>n</i>-C<sub>3</sub>H<sub>7</sub>)<sub>4</sub>N[Fe<sup>II</sup>Fe<sup>III</sup>(dto)<sub>3</sub>] (dto = dithiooxalato) undergoes a novel charge-transfer phase...

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Bibliographic Details
Main Authors: Masaya Enomoto, Hiromichi Ida, Atsushi Okazawa, Norimichi Kojima
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Crystals
Subjects:
charge-transfer phase transition
iron mixed-valence complex
hetero metal complex
dithiooxalato ligand
substitution of 3d transition metal ion
ferromagnetism
dielectric response
<sup>57</sup>Fe Mössbauer spectroscopy
Online Access:https://www.mdpi.com/2073-4352/8/12/446

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