Li0.17Na5.83Mo11O36

Li0.17Na5.83Mo11O36

The title mixed-alkali-metal molybdenium oxide, hexakis(lithium/sodium) undecamolybdate, was synthesized by solid-state reaction at 793 K. Its [Mo11O36]6− framework is built up from MoO6 octahedra and MoO5 pyramids linked together by edges and vertices. The framework deli...

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Main Authors: Ines Ennajeh, Hamadi Hamza, Mohamed Faouzi Zid, Ahmed Driss
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812044224
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spelling doaj-9eb77683d11c49a78464c2d3f157968a2020-11-25T02:14:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812i88i8810.1107/S1600536812044224Li0.17Na5.83Mo11O36Ines EnnajehHamadi HamzaMohamed Faouzi ZidAhmed DrissThe title mixed-alkali-metal molybdenium oxide, hexakis(lithium/sodium) undecamolybdate, was synthesized by solid-state reaction at 793 K. Its [Mo11O36]6− framework is built up from MoO6 octahedra and MoO5 pyramids linked together by edges and vertices. The framework delimits two types of intersecting tunnels running along [100] and [001], where the sodium and lithium ions are located. Two of the sodium ions and the lithium ion have fractional site occupancies. One of the Mo atoms has site symmetry 2, one sodium ion has site symmetry 2 and one has site symmetry -1, and the Li+ ion has site symmetry 2. Structural relationships between the title compound and the anatase and Na6Mo11O36 structures are discussed.http://scripts.iucr.org/cgi-bin/paper?S1600536812044224
collection DOAJ
language English
format Article
sources DOAJ
author Ines Ennajeh
Hamadi Hamza
Mohamed Faouzi Zid
Ahmed Driss
spellingShingle Ines Ennajeh
Hamadi Hamza
Mohamed Faouzi Zid
Ahmed Driss
Li0.17Na5.83Mo11O36
Acta Crystallographica Section E
author_facet Ines Ennajeh
Hamadi Hamza
Mohamed Faouzi Zid
Ahmed Driss
author_sort Ines Ennajeh
title Li0.17Na5.83Mo11O36
title_short Li0.17Na5.83Mo11O36
title_full Li0.17Na5.83Mo11O36
title_fullStr Li0.17Na5.83Mo11O36
title_full_unstemmed Li0.17Na5.83Mo11O36
title_sort li0.17na5.83mo11o36
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description The title mixed-alkali-metal molybdenium oxide, hexakis(lithium/sodium) undecamolybdate, was synthesized by solid-state reaction at 793 K. Its [Mo11O36]6− framework is built up from MoO6 octahedra and MoO5 pyramids linked together by edges and vertices. The framework delimits two types of intersecting tunnels running along [100] and [001], where the sodium and lithium ions are located. Two of the sodium ions and the lithium ion have fractional site occupancies. One of the Mo atoms has site symmetry 2, one sodium ion has site symmetry 2 and one has site symmetry -1, and the Li+ ion has site symmetry 2. Structural relationships between the title compound and the anatase and Na6Mo11O36 structures are discussed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812044224
work_keys_str_mv AT inesennajeh li017na583mo11o36
AT hamadihamza li017na583mo11o36
AT mohamedfaouzizid li017na583mo11o36
AT ahmeddriss li017na583mo11o36
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