Di-μ-bromido-bis[benzyl(diethyl ether)magnesium]
The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-molecule, the structural dimeric unit being generated by inversion symmetry with a...
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812025445 |
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doaj-9e8583ce7b7748ddb19de39815773ab52020-11-24T21:28:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m942m94210.1107/S1600536812025445Di-μ-bromido-bis[benzyl(diethyl ether)magnesium]Mark A. NesbitDanielle L. GrayGregory S. GirolamiThe title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-molecule, the structural dimeric unit being generated by inversion symmetry with an Mg...Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals interactions only.http://scripts.iucr.org/cgi-bin/paper?S1600536812025445 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Mark A. Nesbit Danielle L. Gray Gregory S. Girolami |
| spellingShingle |
Mark A. Nesbit Danielle L. Gray Gregory S. Girolami Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] Acta Crystallographica Section E |
| author_facet |
Mark A. Nesbit Danielle L. Gray Gregory S. Girolami |
| author_sort |
Mark A. Nesbit |
| title |
Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
| title_short |
Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
| title_full |
Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
| title_fullStr |
Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
| title_full_unstemmed |
Di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
| title_sort |
di-μ-bromido-bis[benzyl(diethyl ether)magnesium] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-07-01 |
| description |
The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-molecule, the structural dimeric unit being generated by inversion symmetry with an Mg...Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals interactions only. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812025445 |
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AT markanesbit diamp956bromidobisbenzyldiethylethermagnesium AT daniellelgray diamp956bromidobisbenzyldiethylethermagnesium AT gregorysgirolami diamp956bromidobisbenzyldiethylethermagnesium |
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