Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units

In this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon pht...

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Main Author: Ağırtaş Mehmet Salih
Format: Article
Language:English
Published: De Gruyter 2020-10-01
Series:Heterocyclic Communications
Subjects:
Online Access:http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0113/hc-2020-0113.xml?format=INT
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spelling doaj-9e369dc6c268485b910679911ce6f4932021-02-28T21:53:15ZengDe GruyterHeterocyclic Communications2191-01972020-10-0126113013610.1515/hc-2020-0113hc-2020-0113Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy unitsAğırtaş Mehmet Salih0Department of Chemistry, Faculty of Science, Van Yuzuncu Yıl University, 65080, Van, TurkeyIn this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon phthalocyanine complex were conducted on the chloroform, dimethyl formamide, dimethyl sulfoxide and tetrahydrofuran solutions. The findings of the fluorescence studies demonstrated that the compound has fluorescence spectra in the different solvents. The effects of the substitution with axially bis-4-tritylphenoxy functionalized groups on these parameters were also compared with the previously synthesized axially disubstituted silicon phthalocyanines. These results proved that the compound has different fluorescence properties in the different solvents.http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0113/hc-2020-0113.xml?format=INTsynthesischaracterizationfluorescencesilicon phthalocyanineaggregationsolubility
collection DOAJ
language English
format Article
sources DOAJ
author Ağırtaş Mehmet Salih
spellingShingle Ağırtaş Mehmet Salih
Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
Heterocyclic Communications
synthesis
characterization
fluorescence
silicon phthalocyanine
aggregation
solubility
author_facet Ağırtaş Mehmet Salih
author_sort Ağırtaş Mehmet Salih
title Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
title_short Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
title_full Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
title_fullStr Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
title_full_unstemmed Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
title_sort fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
publisher De Gruyter
series Heterocyclic Communications
issn 2191-0197
publishDate 2020-10-01
description In this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon phthalocyanine complex were conducted on the chloroform, dimethyl formamide, dimethyl sulfoxide and tetrahydrofuran solutions. The findings of the fluorescence studies demonstrated that the compound has fluorescence spectra in the different solvents. The effects of the substitution with axially bis-4-tritylphenoxy functionalized groups on these parameters were also compared with the previously synthesized axially disubstituted silicon phthalocyanines. These results proved that the compound has different fluorescence properties in the different solvents.
topic synthesis
characterization
fluorescence
silicon phthalocyanine
aggregation
solubility
url http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0113/hc-2020-0113.xml?format=INT
work_keys_str_mv AT agırtasmehmetsalih fluorescencepropertiesindifferentsolventsandsynthesisofaxiallysubstitutedsiliconphthalocyaninebearingbis4tritylphenoxyunits
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