Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
In this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon pht...
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doaj-9e369dc6c268485b910679911ce6f4932021-02-28T21:53:15ZengDe GruyterHeterocyclic Communications2191-01972020-10-0126113013610.1515/hc-2020-0113hc-2020-0113Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy unitsAğırtaş Mehmet Salih0Department of Chemistry, Faculty of Science, Van Yuzuncu Yıl University, 65080, Van, TurkeyIn this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon phthalocyanine complex were conducted on the chloroform, dimethyl formamide, dimethyl sulfoxide and tetrahydrofuran solutions. The findings of the fluorescence studies demonstrated that the compound has fluorescence spectra in the different solvents. The effects of the substitution with axially bis-4-tritylphenoxy functionalized groups on these parameters were also compared with the previously synthesized axially disubstituted silicon phthalocyanines. These results proved that the compound has different fluorescence properties in the different solvents.http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0113/hc-2020-0113.xml?format=INTsynthesischaracterizationfluorescencesilicon phthalocyanineaggregationsolubility |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ağırtaş Mehmet Salih |
spellingShingle |
Ağırtaş Mehmet Salih Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units Heterocyclic Communications synthesis characterization fluorescence silicon phthalocyanine aggregation solubility |
author_facet |
Ağırtaş Mehmet Salih |
author_sort |
Ağırtaş Mehmet Salih |
title |
Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units |
title_short |
Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units |
title_full |
Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units |
title_fullStr |
Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units |
title_full_unstemmed |
Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units |
title_sort |
fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units |
publisher |
De Gruyter |
series |
Heterocyclic Communications |
issn |
2191-0197 |
publishDate |
2020-10-01 |
description |
In this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon phthalocyanine complex were conducted on the chloroform, dimethyl formamide, dimethyl sulfoxide and tetrahydrofuran solutions. The findings of the fluorescence studies demonstrated that the compound has fluorescence spectra in the different solvents. The effects of the substitution with axially bis-4-tritylphenoxy functionalized groups on these parameters were also compared with the previously synthesized axially disubstituted silicon phthalocyanines. These results proved that the compound has different fluorescence properties in the different solvents. |
topic |
synthesis characterization fluorescence silicon phthalocyanine aggregation solubility |
url |
http://www.degruyter.com/view/j/hc.2020.26.issue-1/hc-2020-0113/hc-2020-0113.xml?format=INT |
work_keys_str_mv |
AT agırtasmehmetsalih fluorescencepropertiesindifferentsolventsandsynthesisofaxiallysubstitutedsiliconphthalocyaninebearingbis4tritylphenoxyunits |
_version_ |
1724247516319318016 |