N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide

In the title compound, C12H9FN2OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 87.08 (16)°] oriented towards the ortho-H atom of the benzene ring. The molecule is nearly planar, the dihedral angle between the thiop...

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Main Authors: Amer M. Alanazi, Siham Lahsasni, Ali A. El-Emam, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811056121
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spelling doaj-9e081c7b638c4314b072fb1ff9154ae02020-11-25T02:19:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682o314o31410.1107/S1600536811056121N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazideAmer M. AlanaziSiham LahsasniAli A. El-EmamSeik Weng NgIn the title compound, C12H9FN2OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 87.08 (16)°] oriented towards the ortho-H atom of the benzene ring. The molecule is nearly planar, the dihedral angle between the thiophene and benzene rings being 13.0 (2)° in the major component. The azomethine C=N double bond in the molecule is of an E configuration. In the crystal, molecules are linked by pairs of N—H...O hydrogen bonds, forming inversion dimers.http://scripts.iucr.org/cgi-bin/paper?S1600536811056121
collection DOAJ
language English
format Article
sources DOAJ
author Amer M. Alanazi
Siham Lahsasni
Ali A. El-Emam
Seik Weng Ng
spellingShingle Amer M. Alanazi
Siham Lahsasni
Ali A. El-Emam
Seik Weng Ng
N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide
Acta Crystallographica Section E
author_facet Amer M. Alanazi
Siham Lahsasni
Ali A. El-Emam
Seik Weng Ng
author_sort Amer M. Alanazi
title N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide
title_short N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide
title_full N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide
title_fullStr N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide
title_full_unstemmed N′-[(1E)-(4-Fluorophenyl)methylidene]thiophene-2-carbohydrazide
title_sort n′-[(1e)-(4-fluorophenyl)methylidene]thiophene-2-carbohydrazide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description In the title compound, C12H9FN2OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 87.08 (16)°] oriented towards the ortho-H atom of the benzene ring. The molecule is nearly planar, the dihedral angle between the thiophene and benzene rings being 13.0 (2)° in the major component. The azomethine C=N double bond in the molecule is of an E configuration. In the crystal, molecules are linked by pairs of N—H...O hydrogen bonds, forming inversion dimers.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811056121
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