Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)

Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)

In the molecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)2(H2O)2](ClO4)2 [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C12H10N6)], the central NiII atom is six-coordinated by a pair of chelating 2-bpt ligands and two water molecules. Intermolecular O—H...N i...

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Main Authors: Li-Chuan Geng, Chun-Fu Shao
Format: Article
Language:English
Published: International Union of Crystallography 2009-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809012598
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spelling doaj-9de4686f3dc54f37ae0933b90fc31bd82020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m511m51210.1107/S1600536809012598Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)Li-Chuan GengChun-Fu ShaoIn the molecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)2(H2O)2](ClO4)2 [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C12H10N6)], the central NiII atom is six-coordinated by a pair of chelating 2-bpt ligands and two water molecules. Intermolecular O—H...N interactions link the monomeric units into a two-dimensional hydrogen-bonded (4,4) network, which is extended to a three-dimensional supramolecular aggregate via π...π stacking interactions [centroid–centroid distances 3.809 (3) and 3.499 (3)  Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536809012598
collection DOAJ
language English
format Article
sources DOAJ
author Li-Chuan Geng
Chun-Fu Shao
spellingShingle Li-Chuan Geng
Chun-Fu Shao
Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
Acta Crystallographica Section E
author_facet Li-Chuan Geng
Chun-Fu Shao
author_sort Li-Chuan Geng
title Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_short Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_full Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_fullStr Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_full_unstemmed Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
title_sort bis(4-amino-3,5-di-2-pyridyl-4h-1,2,4-triazole)diaquanickel(ii) bis(perchlorate)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-05-01
description In the molecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)2(H2O)2](ClO4)2 [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C12H10N6)], the central NiII atom is six-coordinated by a pair of chelating 2-bpt ligands and two water molecules. Intermolecular O—H...N interactions link the monomeric units into a two-dimensional hydrogen-bonded (4,4) network, which is extended to a three-dimensional supramolecular aggregate via π...π stacking interactions [centroid–centroid distances 3.809 (3) and 3.499 (3)  Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536809012598
work_keys_str_mv AT lichuangeng bis4amino35di2pyridyl4h124triazolediaquanickeliibisperchlorate
AT chunfushao bis4amino35di2pyridyl4h124triazolediaquanickeliibisperchlorate
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