Synthesis and Single Crystal Structures of <i>N</i>-Substituted Benzamides and Their Chemoselective Selenation/Reduction Derivatives

Synthesis and Single Crystal Structures of <i>N</i>-Substituted Benzamides and Their Chemoselective Selenation/Reduction Derivatives

A series of <i>N</i>-aryl-<i>N</i>-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins’ reagent, a highly efficient chemoselective selenation/reduction reagent, gave the corresponding <i>N</i>-aryl-<i>...

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Bibliographic Details
Main Authors: Guoxiong Hua, Cameron L. Carpenter-Warren, David B. Cordes, Alexandra M. Z. Slawin, J. Derek Woollins
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Molecules
Subjects:
<i>N</i>-Substituted Benzamides
Woollins’ reagent
selenation reagent
reduction reagent
single crystal X-ray structures
Online Access:https://www.mdpi.com/1420-3049/26/8/2367
Description
Summary:A series of <i>N</i>-aryl-<i>N</i>-(2-oxo-2-arylethyl) benzamides and cinnamides has been prepared. The reaction of the benzamides with Woollins’ reagent, a highly efficient chemoselective selenation/reduction reagent, gave the corresponding <i>N</i>-aryl-<i>N</i>-(arylenethyl) benzoselenoamides in good yields. Five representative single crystal X-ray structures are discussed.
ISSN:1420-3049

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