| Summary: | In this study, salicylhydroxamic acid (SHA), which exhibits superior flotation performance to conventional collector benzohydroxamic acid (BHA), was first introduced in ilmenite flotation. The addition of lead(II) can significantly increase the recovery of ilmenite using SHA as collector. Thus, the adsorption mechanism of SHA on lead(II)-activated ilmenite surface was systematically studied using micro-flotation tests, adsorption analysis, zeta potential measurements, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Micro-flotation results revealed that SHA had stronger collecting ability than BHA, and ilmenite floatability could be activated by lead ions with either SHA or BHA as collector. Ilmenite showed good floatability at pH 6–8 (over 90% recovery) in the presence of Pb<sup>2+</sup> and SHA. In such conditions, the main lead species of Pb(OH)<sup>+</sup> and Pb<sup>2+</sup> acted as active sites and caused positive surface potential shifts, thereby increasing the adsorbed amounts of negatively charged SHA on the surface of the mineral. FTIR and XPS analyses suggested that the lead species was chemically adsorbed on the surface of ilmenite to form active sites chelated by SHA. Moreover, the free lead ions in solution might form the Pb–SHA complexes to adsorb on the mineral surface, thereby increasing the floatability of ilmenite.
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