Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution

Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution

Organic electrode materials could enable novelty chemistry required by the new generation of batteries. Here the authors show the synthesis and electrochemical performance of Mg(Li2)-p-DHT as a lithiated cathode material that cycles at 3.4 V due to the presence of a spectator cation in the host stru...

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Main Authors: Alia Jouhara, Nicolas Dupré, Anne-Claire Gaillot, Dominique Guyomard, Franck Dolhem, Philippe Poizot
Format: Article
Language:English
Published: Nature Publishing Group 2018-10-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-06708-x
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spelling doaj-9c3c61b7afa1429cb79fb58ec2aef5312021-05-11T09:22:22ZengNature Publishing GroupNature Communications2041-17232018-10-019111110.1038/s41467-018-06708-xRaising the redox potential in carboxyphenolate-based positive organic materials via cation substitutionAlia Jouhara0Nicolas Dupré1Anne-Claire Gaillot2Dominique Guyomard3Franck Dolhem4Philippe Poizot5Institut des Matériaux Jean Rouxel (IMN), UMR CNRS 6502, Université de NantesInstitut des Matériaux Jean Rouxel (IMN), UMR CNRS 6502, Université de NantesInstitut des Matériaux Jean Rouxel (IMN), UMR CNRS 6502, Université de NantesInstitut des Matériaux Jean Rouxel (IMN), UMR CNRS 6502, Université de NantesLaboratoire de Glycochimie, des Antimicrobiens et des Agroressources (LG2A), UMR CNRS 7378, Université de Picardie Jules VerneInstitut des Matériaux Jean Rouxel (IMN), UMR CNRS 6502, Université de NantesOrganic electrode materials could enable novelty chemistry required by the new generation of batteries. Here the authors show the synthesis and electrochemical performance of Mg(Li2)-p-DHT as a lithiated cathode material that cycles at 3.4 V due to the presence of a spectator cation in the host structure.https://doi.org/10.1038/s41467-018-06708-x
collection DOAJ
language English
format Article
sources DOAJ
author Alia Jouhara
Nicolas Dupré
Anne-Claire Gaillot
Dominique Guyomard
Franck Dolhem
Philippe Poizot
spellingShingle Alia Jouhara
Nicolas Dupré
Anne-Claire Gaillot
Dominique Guyomard
Franck Dolhem
Philippe Poizot
Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
Nature Communications
author_facet Alia Jouhara
Nicolas Dupré
Anne-Claire Gaillot
Dominique Guyomard
Franck Dolhem
Philippe Poizot
author_sort Alia Jouhara
title Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
title_short Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
title_full Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
title_fullStr Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
title_full_unstemmed Raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
title_sort raising the redox potential in carboxyphenolate-based positive organic materials via cation substitution
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2018-10-01
description Organic electrode materials could enable novelty chemistry required by the new generation of batteries. Here the authors show the synthesis and electrochemical performance of Mg(Li2)-p-DHT as a lithiated cathode material that cycles at 3.4 V due to the presence of a spectator cation in the host structure.
url https://doi.org/10.1038/s41467-018-06708-x
work_keys_str_mv AT aliajouhara raisingtheredoxpotentialincarboxyphenolatebasedpositiveorganicmaterialsviacationsubstitution
AT nicolasdupre raisingtheredoxpotentialincarboxyphenolatebasedpositiveorganicmaterialsviacationsubstitution
AT anneclairegaillot raisingtheredoxpotentialincarboxyphenolatebasedpositiveorganicmaterialsviacationsubstitution
AT dominiqueguyomard raisingtheredoxpotentialincarboxyphenolatebasedpositiveorganicmaterialsviacationsubstitution
AT franckdolhem raisingtheredoxpotentialincarboxyphenolatebasedpositiveorganicmaterialsviacationsubstitution
AT philippepoizot raisingtheredoxpotentialincarboxyphenolatebasedpositiveorganicmaterialsviacationsubstitution
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