N-Benzylidenenordehydroabietylamine

N-Benzylidenenordehydroabietylamine

The title compound [systematic name: (1R,4aS,10aR,E)-N-benzylidene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-amine], C26H33N, has been synthesized from nor-dehydroabietylamine and benzaldehyde. The two cyclohexane rings form a trans ring junction with classic chair and hal...

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Main Authors: Xiao-Ping Rao, Yong Wu, Zhan-Qian Song, Shi-Bin Shang
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809022909
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spelling doaj-9c356b9b9e9049c1ba3a293e7cadc9572020-11-25T01:52:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657o1639o163910.1107/S1600536809022909N-BenzylidenenordehydroabietylamineXiao-Ping RaoYong WuZhan-Qian SongShi-Bin ShangThe title compound [systematic name: (1R,4aS,10aR,E)-N-benzylidene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-amine], C26H33N, has been synthesized from nor-dehydroabietylamine and benzaldehyde. The two cyclohexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, the two methyl groups are on the same side of tricyclic hydrophenanthrene structure. The dihedral angle between two benzene rings is 44.2 (4)°. The C=N bond is in an E configuration. http://scripts.iucr.org/cgi-bin/paper?S1600536809022909
collection DOAJ
language English
format Article
sources DOAJ
author Xiao-Ping Rao
Yong Wu
Zhan-Qian Song
Shi-Bin Shang
spellingShingle Xiao-Ping Rao
Yong Wu
Zhan-Qian Song
Shi-Bin Shang
N-Benzylidenenordehydroabietylamine
Acta Crystallographica Section E
author_facet Xiao-Ping Rao
Yong Wu
Zhan-Qian Song
Shi-Bin Shang
author_sort Xiao-Ping Rao
title N-Benzylidenenordehydroabietylamine
title_short N-Benzylidenenordehydroabietylamine
title_full N-Benzylidenenordehydroabietylamine
title_fullStr N-Benzylidenenordehydroabietylamine
title_full_unstemmed N-Benzylidenenordehydroabietylamine
title_sort n-benzylidenenordehydroabietylamine
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-07-01
description The title compound [systematic name: (1R,4aS,10aR,E)-N-benzylidene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-amine], C26H33N, has been synthesized from nor-dehydroabietylamine and benzaldehyde. The two cyclohexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, the two methyl groups are on the same side of tricyclic hydrophenanthrene structure. The dihedral angle between two benzene rings is 44.2 (4)°. The C=N bond is in an E configuration.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809022909
work_keys_str_mv AT xiaopingrao nbenzylidenenordehydroabietylamine
AT yongwu nbenzylidenenordehydroabietylamine
AT zhanqiansong nbenzylidenenordehydroabietylamine
AT shibinshang nbenzylidenenordehydroabietylamine
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