Poly[3-methyl-1,3-oxazolidin-2-iminium[µ<sub>3</sub>-cyanido-tri-µ<sub>2</sub>-cyanido-κ<sup>9</sup>C:N-tricuprate(I)]]

Poly[3-methyl-1,3-oxazolidin-2-iminium[µ<sub>3</sub>-cyanido-tri-µ<sub>2</sub>-cyanido-κ<sup>9</sup>C:N-tricuprate(I)]]

The unexpected formation of an oxazole ring has occurred during synthesis of a copper(I) cyanide network polymer as part of our ongoing studies of the structural chemistry of these networks. Crystals of the title compound were formed during the synthesis of a previously reported CuCN network solid c...

Full description

Bibliographic Details
Main Authors:	Leena N. Rachid, Peter W. R. Corfield
Format:	Article
Language:	English
Published:	MDPI AG 2021-07-01
Series:	Molbank
Subjects:	oxazole iminium unexpected product copper cyanide network cuprophilic
Online Access:	https://www.mdpi.com/1422-8599/2021/3/M1259

Similar Items

Poly[1,3-Dimethyltetrahydropyrimidin-2(1<i>H</i>)-iminium [tri-µ<sub>2</sub>-cyanido-κ<sup>6</sup>C:N-dicuprate(I)]]
by: Peter W. R. Corfield, et al.
Published: (2020-11-01)

Poly[diethylammonium [tetra-μ2-cyanido-κ8C:N-tricuprate(I)]], a two-dimensional network solid
by: Peter W. R. Corfield, et al.
Published: (2020-07-01)

Crystal structure of poly[N,N-diethyl-2-hydroxyethan-1-aminium [μ3-cyanido-κ3C:C:N-di-μ-cyanido-κ4C:N-dicuprate(I)]]
by: Peter W. R. Corfield, et al.
Published: (2016-07-01)

Crystal structure of catena-poly[[[(2-ethoxypyrazine-κN)copper(I)]-di-μ2-cyanido] [copper(I)-μ2-cyanido]]
by: Sofiia V. Partsevska, et al.
Published: (2019-11-01)

Cyanide Complexes Based on {Mo<sub>6</sub>I<sub>8</sub>}<sup>4+</sup> and {W<sub>6</sub>I<sub>8</sub>}<sup>4+</sup> Cluster Cores
by: Aleksei S. Pronin, et al.
Published: (2020-12-01)

Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh<sub>3</sub>)(Br)]<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>, [Pd(Br)]<sub>2</sub>(μ,η<sup>2</sup>-Hdppa)<sub>2</sub>, and [{Pd(PPh<sub>3</sub>)(CH<sub>3</sub>CN)}<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>][BF<sub>4</sub>]<sub>2</sub>
by: Hsiao-Fen Wang, et al.
Published: (2020-04-01)

Crystal structures of two mixed-valence copper cyanide complexes with N-methylethylenediamine
by: Peter W. R. Corfield, et al.
Published: (2017-02-01)

Crystal structure of a low-spin poly[di-μ3-cyanido-di-μ2-cyanido-bis(μ2-2-ethylpyrazine)dicopper(I)iron(II)]
by: Sofiia V. Partsevska, et al.
Published: (2019-08-01)

Contribution of Cation-π Interactions in Iminium Catalysis
by: Yukie Mori, et al.
Published: (2012-02-01)

Crystal structure of catena-poly[[gold(I)-μ-cyanido-[diaquabis(2-phenylpyrazine)iron(II)]-μ-cyanido] dicyanidogold(I)]
by: Olesia I. Kucheriv, et al.
Published: (2019-08-01)

Reactions of 3-aryl-1-(trifluoromethyl)prop-2-yn-1-iminium salts with 1,3-dienes and styrenes
by: Thomas Schneider, et al.
Published: (2020-08-01)

Na<sub>3</sub>[Ru<sub>2</sub>(<i>µ-</i>CO<sub>3</sub>)<sub>4</sub>] as a Homogeneous Catalyst for Water Oxidation; HCO<sub>3</sub><sup>−</sup> as a Co-Catalyst
by: Shanti Gopal Patra, et al.
Published: (2021-02-01)

Crystal structure of poly[(2,2′-bipyridine-κ2N,N′)tetrakis(μ-cyanido-κ2N:C)dinickel(II)]
by: Minghui Zuo, et al.
Published: (2015-06-01)

catena-Poly[[bis(quinolin-8-amine-κ2N,N′)cadmium(II)]-μ-cyanido-κ2N:C-[dicyanidonickel(II)]-μ-cyanido-κ2C:N]
by: Selma Khelfa, et al.
Published: (2021-06-01)

Iminium Salts by Meerwein Alkylation of Ehrlich’s Aldehyde
by: Gerhard Laus, et al.
Published: (2013-03-01)

Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)cobalt(II)]-μ-cyanido-κ2N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ2C:N]
by: Frankie White, et al.
Published: (2014-09-01)

New Photomagnetic Ionic Salts Based on [Mo<sup>IV</sup>(CN)<sub>8</sub>]<sup>4−</sup> and [W<sup>IV</sup>(CN)<sub>8</sub>]<sup>4−</sup> Anions
by: Xinghui Qi, et al.
Published: (2021-07-01)

Modeling of the Refractive Index for the Systems MX+H<sub>2</sub>O, M<sub>2</sub>X+H<sub>2</sub>O, H<sub>3</sub>BO<sub>3</sub>+MX+H<sub>2</sub>O, and H<sub>3</sub>BO<sub>3</sub>+M<sub>2</sub>X+H<sub>2</sub>O. M = K<sup>+</sup>, Na<sup>+</sup>, or Li<sup>+</sup> and X = Cl<sup>−</sup> or SO<sub>4</sub><sup>2</sup><sup>−</sup>
by: Wilson Alavia, et al.
Published: (2021-03-01)

Coordination Behavior of [Cp″<sub>2</sub>Zr(µ<sup>1:1</sup>-As<sub>4</sub>)] towards Lewis Acids
by: Veronika Heinl, et al.
Published: (2021-05-01)

Spontaneous Magnetization and Optical Activity in the Chiral Series {(L-proline)<i><sub>n</sub></i>V[Cr(CN)<sub>6</sub>]<i><sub>x</sub></i>} (0 < <i>n</i> < 3)
by: Bárbara Rodríguez-García, et al.
Published: (2020-03-01)

Enantioselective additions of copper acetylides to cyclic iminium and oxocarbenium ions
by: Jixin Liu, et al.
Published: (2015-12-01)

Determination of Thermoluminescence Kinetic Parameters of La<sub>2</sub>O<sub>3</sub> Doped with Dy<sup>3+</sup> and Eu<sup>3+</sup>
by: Mahmoud Bakr, et al.
Published: (2020-02-01)

Characterization and Luminescence of Eu<sup>3+</sup>- and Gd<sup>3+</sup>-Doped Hydroxyapatite Ca<sub>10</sub>(Po<sub>4</sub>)<sub>6</sub>(Oh)<sub>2</sub>
by: Veronica Paterlini, et al.
Published: (2020-09-01)

FERROELECTRIC PROPERTIES OF BaBi<sub>4</sub>T<sub>i4</sub>O<sub>15</sub> DOPED WITH Pb<sup>2+</sup>, Al<sup>3+</sup>, Ga<sup>3+</sup>, In<sup>3+</sup>, Ta<sup>5+</sup> AURIVILLIUS PHASES
by: Afifah Rosyidah, et al.
Published: (2010-06-01)

Luminescence Properties of Co-Doped Eu<sup>3+</sup>, Bi<sup>3+</sup> Lu<sub>2</sub>O<sub>3</sub>/Polyvinylpyrrolidone Films
by: Ángel de Jesús Morales-Ramírez, et al.
Published: (2018-11-01)

Research on Molecular Structure and Electronic Properties of Ln<sup>3+</sup> (Ce<sup>3+</sup>, Tb<sup>3+</sup>, Pr<sup>3+</sup>)/Li<sup>+</sup> and Eu<sup>2+</sup> Co-Doped Sr<sub>2</sub>Si<sub>5</sub>N<sub>8</sub> via DFT Calculation
by: Ziqian Yin, et al.
Published: (2021-03-01)

Feasibility of Adjusting the S<sub>2</sub>O<sub>3</sub><sup>2−</sup>/NO<sub>3</sub><sup>−</sup> Ratio to Adapt to Dynamic Influents in Coupled Anammox and Denitrification Systems
by: Yuqian Hou, et al.
Published: (2020-03-01)

The phosphine-exchange reaction with an equimolar mixture of [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO) <sub>2</sub>PPh<sub>3</sub>]<sup>+</sup>[PF<sub>6</sub>]<sup>-</sup> and P(2-C<sub>4</sub>H<sub>3</sub>O)<sub>3</sub> (C4H3O = furanyl)
by: O.G. Adeyemi, et al.
Published: (2001-06-01)

Introduction of Re(CO)<sub>3</sub><sup>+</sup>/<sup>99m</sup>Tc(CO)<sub>3</sub><sup>+</sup> Organometallic Species into Vinylpyrrolidone-Allyliminodiacetate Copolymers
by: Nikolay Ivanovich Gorshkov, et al.
Published: (2021-06-01)

Single and Double-Stranded 1D-Coordination Polymers with 4′-(4-Alkyloxyphenyl)-3,2′:6′,3″-terpyridines and {Cu<sub>2</sub>(μ-OAc)<sub>4</sub>} or {Cu<sub>4</sub>(μ<sub>3</sub>-OH)<sub>2</sub>(μ-OAc)<sub>2</sub>(μ<sub>3</sub>-OAc)<sub>2</sub>(AcO-κ<i>O</i>)<sub>2</sub>} Motifs
by: Dalila Rocco, et al.
Published: (2020-02-01)

μ-Cyanido-κ2C:N-dicyanido-κ2C-bis(N-ethylethylenediamine-κ2N,N′)copper(II)copper(I)
by: Peter W. R. Corfield, et al.
Published: (2014-02-01)

New Quaternary Chalcogenides Tl<sub>2</sub>M<sup>II</sup>M<sup>IV</sup><sub>3</sub>Se<sub>8</sub> and Tl<sub>2</sub>M<sup>II</sup>M<sup>IV</sup>X<sub>4</sub>
by: Andrii Selezen, et al.
Published: (2020-12-01)

Uptake of Radionuclides <sup>60</sup>Co, <sup>137</sup>Cs, and <sup>90</sup>Sr with α-Fe<sub>2</sub>O<sub>3</sub> and Fe<sub>3</sub>O<sub>4</sub> Particles from Aqueous Environment
by: Natalya V. Efimova, et al.
Published: (2021-05-01)

catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N]
by: Lucia Piñeiro-López, et al.
Published: (2017-10-01)

Optimization of the Synthesis and Energy Transfer of Ca<sub>2</sub>MgWO<sub>6</sub>:Cr<sup>3+</sup>,Nd<sup>3+</sup>
by: Viktor Anselm, et al.
Published: (2021-03-01)

Development of iminium ion cascade methodologies and their application to the synthesis of complex molecules
by: Jewett, Ivan Tucker
Published: (2015)

Nightglow vibrational distributions in the A<sup>3</sup>Σ<sub>u</sub><sup>+</sup> and A'<sup>3</sup>Δ<sub>u</sub> states of O<sub>2</sub> derived from astronomical sky spectra
by: T. G. Slanger, et al.
Published: (2004-09-01)

Infrared and Raman Spectroscopy of Ammoniovoltaite, (NH<sub>4</sub>)<sub>2</sub>Fe<sup>2+</sup><sub>5</sub>Fe<sup>3+</sup><sub>3</sub>Al(SO<sub>4</sub>)<sub>12</sub>(H<sub>2</sub>O)<sub>18</sub>
by: Anastasia V. Sergeeva, et al.
Published: (2020-09-01)

Poly[bis(trimethylammonium) [hexa-μ-cyanido-cadmium(II)dicopper(I)]]
by: Shin-ichi Nishikiori, et al.
Published: (2017-12-01)

Cu<sup>II</sup>- and Co<sup>II</sup>-Based MOFs: {[La<sub>2</sub>Cu<sub>3</sub>(µ-H<sub>2</sub>O)(ODA)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>]∙3H<sub>2</sub>O}<sub>n</sub> and {[La<sub>2</sub>Co<sub>3</sub>(ODA)<sub>6</sub>(H<sub>2</sub>O)<sub>6</sub>]∙12H<sub>2</sub>O}<sub>n</sub>. The Relevance of Physicochemical Properties on the Catalytic Aerobic Oxidation of Cyclohexene
by: Luis Santibáñez, et al.
Published: (2020-05-01)