New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation

New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation

The tetra dentate neutral (E)-4-nitro-2-((2-(2-(pyridin-2-yl) ethylthio) ethylimino) methyl) phenol, (pytaO2NSalH), Schiff-base ligand was synthesized using 1-(2-pyridyl)-3-thia-s-aminopentane (pyta) and 5-NO2 salicylaldehyde. Then the related square planar Pt (II) cationic complex, [Pt (NSNO)] Cl,...

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Main Authors: Alireza Akbari, Iran Sheikhshoaie, Lotfali Saghatforoush, S. Yousof Ebrahimipour, Zohreh Amiri
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/802529
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spelling doaj-9b965fce083443eaa9177aa7c9806ffe2020-11-24T22:38:59ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102012-01-01942114211810.1155/2012/802529New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT CalculationAlireza Akbari0Iran Sheikhshoaie1Lotfali Saghatforoush2S. Yousof Ebrahimipour3Zohreh Amiri4Department of Chemistry, Payame Noor University, 19395-4697, Tehran, IranDepartment of Chemistry, Payame Noor University, 19395-4697, Tehran, IranDepartment of Chemistry, Payame Noor University, 19395-4697, Tehran, IranDepartment of Chemistry, Payame Noor University, 19395-4697, Tehran, IranDepartment of Chemistry, Payame Noor University, 19395-4697, Tehran, IranThe tetra dentate neutral (E)-4-nitro-2-((2-(2-(pyridin-2-yl) ethylthio) ethylimino) methyl) phenol, (pytaO2NSalH), Schiff-base ligand was synthesized using 1-(2-pyridyl)-3-thia-s-aminopentane (pyta) and 5-NO2 salicylaldehyde. Then the related square planar Pt (II) cationic complex, [Pt (NSNO)] Cl, was synthesized using PtCl2 (SMe2)2 as precursor complex. The nature of the pytaO2NSalH and its platinum complex were determined by the elemental analysis, molar conductivity and spectrochemical (IR, UV–vis, 1HNMR) techniques. In addition, the fully optimized geometries and vibration frequencies of them together were calculated using the ADF 2009.01 package. Structural parameters are in good agreement with the experimental data. The calculated and experimental results confirmed the suggested structures for the ligand and complex.http://dx.doi.org/10.1155/2012/802529
collection DOAJ
language English
format Article
sources DOAJ
author Alireza Akbari
Iran Sheikhshoaie
Lotfali Saghatforoush
S. Yousof Ebrahimipour
Zohreh Amiri
spellingShingle Alireza Akbari
Iran Sheikhshoaie
Lotfali Saghatforoush
S. Yousof Ebrahimipour
Zohreh Amiri
New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation
E-Journal of Chemistry
author_facet Alireza Akbari
Iran Sheikhshoaie
Lotfali Saghatforoush
S. Yousof Ebrahimipour
Zohreh Amiri
author_sort Alireza Akbari
title New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation
title_short New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation
title_full New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation
title_fullStr New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation
title_full_unstemmed New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation
title_sort new platinum(ii) complex containing asymmetric tetra dentate schiff base ligand synthesis, characterization and dft calculation
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2012-01-01
description The tetra dentate neutral (E)-4-nitro-2-((2-(2-(pyridin-2-yl) ethylthio) ethylimino) methyl) phenol, (pytaO2NSalH), Schiff-base ligand was synthesized using 1-(2-pyridyl)-3-thia-s-aminopentane (pyta) and 5-NO2 salicylaldehyde. Then the related square planar Pt (II) cationic complex, [Pt (NSNO)] Cl, was synthesized using PtCl2 (SMe2)2 as precursor complex. The nature of the pytaO2NSalH and its platinum complex were determined by the elemental analysis, molar conductivity and spectrochemical (IR, UV–vis, 1HNMR) techniques. In addition, the fully optimized geometries and vibration frequencies of them together were calculated using the ADF 2009.01 package. Structural parameters are in good agreement with the experimental data. The calculated and experimental results confirmed the suggested structures for the ligand and complex.
url http://dx.doi.org/10.1155/2012/802529
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