(C-meso-N-meso-5,12-Dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)copper(II) bis[O,O′-bis(4-methylphenyl)dithiophosphate]
In the title compound, [Cu(C24H32N4)](C14H14O2PS2)2, the CuII atom lies on an inversion center and is chelated by the macrocyclic ligand in a distorted CuN4 square-planar geometry. Two O,O′-bis(4-methylphenyl)dithiophosphate anions occupy the axial positions with long Cu...S distances...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810046672 |
| Summary: | In the title compound, [Cu(C24H32N4)](C14H14O2PS2)2, the CuII atom lies on an inversion center and is chelated by the macrocyclic ligand in a distorted CuN4 square-planar geometry. Two O,O′-bis(4-methylphenyl)dithiophosphate anions occupy the axial positions with long Cu...S distances of 3.0090 (8) Å. Intermolecular N—H...S and C—H...S hydrogen bonding is present between the anions and the cation. |
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| ISSN: | 1600-5368 |