Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate

Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate

In the title compound, [Co(C13H9ClN3O)2]NO3·1.5H2O, the central Co3+ atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully oc...

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Main Authors: Genhua Wu, Dayu Wu, Hui Ye, Yan Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681004612X
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spelling doaj-9b87b5185c4e406cb76f431add330d4a2020-11-25T01:33:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1568m156910.1107/S160053681004612XBis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrateGenhua WuDayu WuHui YeYan ZhaoIn the title compound, [Co(C13H9ClN3O)2]NO3·1.5H2O, the central Co3+ atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water molecules, and the nitrate anion via classical intermolecular O—H...O and O—H...N hydrogen bonds and weak C—H...O contacts. http://scripts.iucr.org/cgi-bin/paper?S160053681004612X
collection DOAJ
language English
format Article
sources DOAJ
author Genhua Wu
Dayu Wu
Hui Ye
Yan Zhao
spellingShingle Genhua Wu
Dayu Wu
Hui Ye
Yan Zhao
Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
Acta Crystallographica Section E
author_facet Genhua Wu
Dayu Wu
Hui Ye
Yan Zhao
author_sort Genhua Wu
title Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_short Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_full Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_fullStr Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_full_unstemmed Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
title_sort bis[4-chloro-n′-(2-pyridylmethylidene)benzohydrazidato]cobalt(iii) nitrate sesquihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the title compound, [Co(C13H9ClN3O)2]NO3·1.5H2O, the central Co3+ atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water molecules, and the nitrate anion via classical intermolecular O—H...O and O—H...N hydrogen bonds and weak C—H...O contacts.
url http://scripts.iucr.org/cgi-bin/paper?S160053681004612X
work_keys_str_mv AT genhuawu bis4chloronamp82422pyridylmethylidenebenzohydrazidatocobaltiiinitratesesquihydrate
AT dayuwu bis4chloronamp82422pyridylmethylidenebenzohydrazidatocobaltiiinitratesesquihydrate
AT huiye bis4chloronamp82422pyridylmethylidenebenzohydrazidatocobaltiiinitratesesquihydrate
AT yanzhao bis4chloronamp82422pyridylmethylidenebenzohydrazidatocobaltiiinitratesesquihydrate
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