Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate

In the title compound, [Co(C13H9ClN3O)2]NO3·1.5H2O, the central Co3+ atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully oc...

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Bibliographic Details
Main Authors: Genhua Wu, Dayu Wu, Hui Ye, Yan Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681004612X
Description
Summary:In the title compound, [Co(C13H9ClN3O)2]NO3·1.5H2O, the central Co3+ atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octahedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water molecules, and the nitrate anion via classical intermolecular O—H...O and O—H...N hydrogen bonds and weak C—H...O contacts.
ISSN:1600-5368