Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase

Adsorption/desorption isotherms from the gaseous phase (benzene vapour, nitrogen) have been determined consecutively a number of times on the same activated carbon sample. The porous structure parameters were evaluated on the basis of the experimental data using the Dubinin-Radushkevich, Dubinin-Ast...

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Main Authors:	Bogdan J. Trznadel, Stefan Zietek, Andrzej Światkowski
Format:	Article
Language:	English
Published:	Hindawi - SAGE Publishing 1999-01-01
Series:	Adsorption Science & Technology
Online Access:	https://doi.org/10.1177/026361749901700102

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spelling	doaj-9b788793ad044b61a6cd4a3167a1245c2021-04-02T10:54:55ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40381999-01-011710.1177/026361749901700102Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous PhaseBogdan J. Trznadel0Stefan Zietek1Andrzej Światkowski2 Military Institute of Chemistry and Radiometry, 00-910 Warsaw, Poland Military Institute of Chemistry and Radiometry, 00-910 Warsaw, Poland Military Technical Academy, 00-908 Warsaw, PolandAdsorption/desorption isotherms from the gaseous phase (benzene vapour, nitrogen) have been determined consecutively a number of times on the same activated carbon sample. The porous structure parameters were evaluated on the basis of the experimental data using the Dubinin-Radushkevich, Dubinin-Astakhov, Finger-Büllow, Dubinin-Stoeckli and Horvath-Kawazoe equations for the calculations. Analyses of the mean values and relative errors of particular structural parameters were made as well as comparisons of the stability of the adsorption models used. It was found that the reliability of the results obtained was better for the benzene vapour adsorption isotherms determined by a gravimetric method than for those determined by a volumetric method using nitrogen as the adsorbate.https://doi.org/10.1177/026361749901700102
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Bogdan J. Trznadel Stefan Zietek Andrzej Światkowski
spellingShingle	Bogdan J. Trznadel Stefan Zietek Andrzej Światkowski Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase Adsorption Science & Technology
author_facet	Bogdan J. Trznadel Stefan Zietek Andrzej Światkowski
author_sort	Bogdan J. Trznadel
title	Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase
title_short	Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase
title_full	Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase
title_fullStr	Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase
title_full_unstemmed	Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase
title_sort	validation of the reliability of the porous structure parameters for activated carbons as evaluated on the basis of adsorption isotherms from the gaseous phase
publisher	Hindawi - SAGE Publishing
series	Adsorption Science & Technology
issn	0263-6174 2048-4038
publishDate	1999-01-01
description	Adsorption/desorption isotherms from the gaseous phase (benzene vapour, nitrogen) have been determined consecutively a number of times on the same activated carbon sample. The porous structure parameters were evaluated on the basis of the experimental data using the Dubinin-Radushkevich, Dubinin-Astakhov, Finger-Büllow, Dubinin-Stoeckli and Horvath-Kawazoe equations for the calculations. Analyses of the mean values and relative errors of particular structural parameters were made as well as comparisons of the stability of the adsorption models used. It was found that the reliability of the results obtained was better for the benzene vapour adsorption isotherms determined by a gravimetric method than for those determined by a volumetric method using nitrogen as the adsorbate.
url	https://doi.org/10.1177/026361749901700102
work_keys_str_mv	AT bogdanjtrznadel validationofthereliabilityoftheporousstructureparametersforactivatedcarbonsasevaluatedonthebasisofadsorptionisothermsfromthegaseousphase AT stefanzietek validationofthereliabilityoftheporousstructureparametersforactivatedcarbonsasevaluatedonthebasisofadsorptionisothermsfromthegaseousphase AT andrzejswiatkowski validationofthereliabilityoftheporousstructureparametersforactivatedcarbonsasevaluatedonthebasisofadsorptionisothermsfromthegaseousphase
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Validation of the Reliability of the Porous Structure Parameters for Activated Carbons as Evaluated on the Basis of Adsorption Isotherms from the Gaseous Phase

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