catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]

In the title polymeric compound, [Mn(N3)2(C13H11N3)2]n, each MnII centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmethyl)-1H-benzimidazole (L) ligands and two azide anions (N3−). Each of the MnII ions lies on an inversion centre. The L ligands and N...

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Main Authors: Chun-Sen Liu, Li-Fen Yan, Jun-Jie Wang
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807062435
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spelling doaj-9af56610b8c24edfb6fcb5034d44cae02020-11-25T00:48:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m29m3010.1107/S1600536807062435catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]Chun-Sen LiuLi-Fen YanJun-Jie WangIn the title polymeric compound, [Mn(N3)2(C13H11N3)2]n, each MnII centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmethyl)-1H-benzimidazole (L) ligands and two azide anions (N3−). Each of the MnII ions lies on an inversion centre. The L ligands and N3− anions bridge adjacent MnII centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536807062435
collection DOAJ
language English
format Article
sources DOAJ
author Chun-Sen Liu
Li-Fen Yan
Jun-Jie Wang
spellingShingle Chun-Sen Liu
Li-Fen Yan
Jun-Jie Wang
catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
Acta Crystallographica Section E
author_facet Chun-Sen Liu
Li-Fen Yan
Jun-Jie Wang
author_sort Chun-Sen Liu
title catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
title_short catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
title_full catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
title_fullStr catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
title_full_unstemmed catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
title_sort catena-poly[[diazidomanganese(ii)]bis[μ-1-(4-pyridylmethyl)-1h-benzimidazole]]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description In the title polymeric compound, [Mn(N3)2(C13H11N3)2]n, each MnII centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmethyl)-1H-benzimidazole (L) ligands and two azide anions (N3−). Each of the MnII ions lies on an inversion centre. The L ligands and N3− anions bridge adjacent MnII centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807062435
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AT junjiewang catenapolydiazidomanganeseiibis95614pyridylmethyl1hbenzimidazole
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