catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]
In the title polymeric compound, [Mn(N3)2(C13H11N3)2]n, each MnII centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmethyl)-1H-benzimidazole (L) ligands and two azide anions (N3−). Each of the MnII ions lies on an inversion centre. The L ligands and N...
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International Union of Crystallography
2008-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807062435 |
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doaj-9af56610b8c24edfb6fcb5034d44cae02020-11-25T00:48:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m29m3010.1107/S1600536807062435catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]]Chun-Sen LiuLi-Fen YanJun-Jie WangIn the title polymeric compound, [Mn(N3)2(C13H11N3)2]n, each MnII centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmethyl)-1H-benzimidazole (L) ligands and two azide anions (N3−). Each of the MnII ions lies on an inversion centre. The L ligands and N3− anions bridge adjacent MnII centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536807062435 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Chun-Sen Liu Li-Fen Yan Jun-Jie Wang |
spellingShingle |
Chun-Sen Liu Li-Fen Yan Jun-Jie Wang catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]] Acta Crystallographica Section E |
author_facet |
Chun-Sen Liu Li-Fen Yan Jun-Jie Wang |
author_sort |
Chun-Sen Liu |
title |
catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]] |
title_short |
catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]] |
title_full |
catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]] |
title_fullStr |
catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]] |
title_full_unstemmed |
catena-Poly[[diazidomanganese(II)]bis[μ-1-(4-pyridylmethyl)-1H-benzimidazole]] |
title_sort |
catena-poly[[diazidomanganese(ii)]bis[μ-1-(4-pyridylmethyl)-1h-benzimidazole]] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-01-01 |
description |
In the title polymeric compound, [Mn(N3)2(C13H11N3)2]n, each MnII centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmethyl)-1H-benzimidazole (L) ligands and two azide anions (N3−). Each of the MnII ions lies on an inversion centre. The L ligands and N3− anions bridge adjacent MnII centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H...N hydrogen bonds. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536807062435 |
work_keys_str_mv |
AT chunsenliu catenapolydiazidomanganeseiibis95614pyridylmethyl1hbenzimidazole AT lifenyan catenapolydiazidomanganeseiibis95614pyridylmethyl1hbenzimidazole AT junjiewang catenapolydiazidomanganeseiibis95614pyridylmethyl1hbenzimidazole |
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