Criteria of thermodynamic similarity: sources and forecast at the molecular level

• Main Author: G.G. Petrik
• Format: Article
• Language: Russian
• Published: Tver State University 2017-12-01
• Series: Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
• Subjects: model of interacting centers; similarity criteria; control factor; spherical shell model; object rigidity; critical compressibility factor; prediction of similarity criteria
• Online Access: http://physchemaspects.ru/archives/2017/fh2017-doi-10-26456-pcascnn-2017-9-363.pdf
• ISSN: 2226-4442; 2658-4360

One more control factor of a new one-parameter family of equations has been added to a number of known thermodynamic similarity criteria. Its relation to the characteristics of the molecular level is established. The results obtained earlier at the atomic-molecular level of modeling objects and interactions make it possible to predict the values of a number of criteria on the basis of minimal information about molecules.