Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)

Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)

The crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C20H14N4)2](PF6)2·H2O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C20H14N4)2](PF6)2·CH3...

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Main Authors: Leandro M. O. Lourenço, Filipe A. Almeida Paz, José A. Fernandes
Format: Article
Language:English
Published: International Union of Crystallography 2015-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
metalloligand
manganese
terpyridine
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015003503
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spelling doaj-9a9ed41d1a834138b9d907211fb77a802020-11-25T00:16:14ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-04-0171433033510.1107/S2056989015003503hg5428Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)Leandro M. O. Lourenço0Filipe A. Almeida Paz1José A. Fernandes2CICECO, Chemistry Department, Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO, Chemistry Department, Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalCICECO, Chemistry Department, Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, PortugalThe crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C20H14N4)2](PF6)2·H2O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C20H14N4)2](PF6)2·CH3COCH3, are described. At 150 K, (1) and (2) have monoclinic (P21/c) and orthorhombic (C2221) symmetries, respectively. Both structures exhibit octahedrally coordinated MnII atoms and disorder. They display weak interactions, such as C—H...F, C—H...N, C—H...π, F...π and π–π. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal.http://scripts.iucr.org/cgi-bin/paper?S2056989015003503crystal structuremetalloligandmanganeseterpyridine
collection DOAJ
language English
format Article
sources DOAJ
author Leandro M. O. Lourenço
Filipe A. Almeida Paz
José A. Fernandes
spellingShingle Leandro M. O. Lourenço
Filipe A. Almeida Paz
José A. Fernandes
Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
metalloligand
manganese
terpyridine
author_facet Leandro M. O. Lourenço
Filipe A. Almeida Paz
José A. Fernandes
author_sort Leandro M. O. Lourenço
title Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
title_short Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
title_full Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
title_fullStr Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
title_full_unstemmed Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate)
title_sort crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(ii) bis(hexafluoridophosphate)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-04-01
description The crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C20H14N4)2](PF6)2·H2O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine]manganese(II) bis(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C20H14N4)2](PF6)2·CH3COCH3, are described. At 150 K, (1) and (2) have monoclinic (P21/c) and orthorhombic (C2221) symmetries, respectively. Both structures exhibit octahedrally coordinated MnII atoms and disorder. They display weak interactions, such as C—H...F, C—H...N, C—H...π, F...π and π–π. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal.
topic crystal structure
metalloligand
manganese
terpyridine
url http://scripts.iucr.org/cgi-bin/paper?S2056989015003503
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