Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate

Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate

In the centrosymmetric dimeric title compound, [Cu2Cl4(C16H20N2O)4]·0.5H2O, the CuII atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamoyl)pyridine liga...

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Main Author: Ying-Chun Wang
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812000670
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spelling doaj-9a8b4c5aeefd4772b143644d5fce79a72020-11-25T01:38:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m147m14710.1107/S1600536812000670Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrateYing-Chun WangIn the centrosymmetric dimeric title compound, [Cu2Cl4(C16H20N2O)4]·0.5H2O, the CuII atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamoyl)pyridine ligands. The amine N atoms are involved in intramolecular N—H...O and intermolecular N—H...Cl hydrogen bonds. The latter hydrogen bonds link the complex molecules into a ribbon along [010]. The uncoordinated water molecule is 0.25-occupied.http://scripts.iucr.org/cgi-bin/paper?S1600536812000670
collection DOAJ
language English
format Article
sources DOAJ
author Ying-Chun Wang
spellingShingle Ying-Chun Wang
Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
Acta Crystallographica Section E
author_facet Ying-Chun Wang
author_sort Ying-Chun Wang
title Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
title_short Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
title_full Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
title_fullStr Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
title_full_unstemmed Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
title_sort di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κn]chloridocopper(ii)} hemihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description In the centrosymmetric dimeric title compound, [Cu2Cl4(C16H20N2O)4]·0.5H2O, the CuII atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamoyl)pyridine ligands. The amine N atoms are involved in intramolecular N—H...O and intermolecular N—H...Cl hydrogen bonds. The latter hydrogen bonds link the complex molecules into a ribbon along [010]. The uncoordinated water molecule is 0.25-occupied.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812000670
work_keys_str_mv AT yingchunwang diamp956chloridobisbis4adamantan1ylcarbamoylpyridineamp954nchloridocopperiihemihydrate
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