{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d8 2.7-solvate

{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d8 2.7-solvate

The molecule of the title compound, [Rh(C42H62O3P)(C74H68O4P2]·2.7C7D8, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/ortho-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a...

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Bibliographic Details
Main Authors: Detlef Selent, Anke Spannenberg, Armin Börner
Format: Article
Language:English
Published: International Union of Crystallography 2016-12-01
Series:IUCrData
Subjects:
crystal structure
rhodium(I) complex
ortho-metallation
bisphosphite
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616019143

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314616019143

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