4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide

4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide

The title compound, C10H10Cl3N3, features a delocalized unsaturated N...;C...;N...;C...;N chain and strong intramolecular N—H...N hydrogen bonding across the chelate ring and also intramolecular N—H...Cl contacts to a CCl3-group Cl atom. The only intermolecular contacts i...

Full description

Bibliographic Details
Main Authors: Tracey L. Roemmele, René T. Boeré
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811044710
id doaj-9a657853a3bd4e43bd3e51cb45c78e39
record_format Article
spelling doaj-9a657853a3bd4e43bd3e51cb45c78e392020-11-25T01:27:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3137o313710.1107/S16005368110447104-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamideTracey L. RoemmeleRené T. BoeréThe title compound, C10H10Cl3N3, features a delocalized unsaturated N...;C...;N...;C...;N chain and strong intramolecular N—H...N hydrogen bonding across the chelate ring and also intramolecular N—H...Cl contacts to a CCl3-group Cl atom. The only intermolecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl3 groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N—C bond between the carboximidamide and imine components [C—N—C—N torsion angle = −23.6 (2) °].http://scripts.iucr.org/cgi-bin/paper?S1600536811044710
collection DOAJ
language English
format Article
sources DOAJ
author Tracey L. Roemmele
René T. Boeré
spellingShingle Tracey L. Roemmele
René T. Boeré
4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
Acta Crystallographica Section E
author_facet Tracey L. Roemmele
René T. Boeré
author_sort Tracey L. Roemmele
title 4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
title_short 4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
title_full 4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
title_fullStr 4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
title_full_unstemmed 4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
title_sort 4-methyl-n′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description The title compound, C10H10Cl3N3, features a delocalized unsaturated N...;C...;N...;C...;N chain and strong intramolecular N—H...N hydrogen bonding across the chelate ring and also intramolecular N—H...Cl contacts to a CCl3-group Cl atom. The only intermolecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl3 groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N—C bond between the carboximidamide and imine components [C—N—C—N torsion angle = −23.6 (2) °].
url http://scripts.iucr.org/cgi-bin/paper?S1600536811044710
work_keys_str_mv AT traceylroemmele 4methylnamp8242222trichloroethanimidoylbenzene1carboximidamide
AT renamp233tboeramp233 4methylnamp8242222trichloroethanimidoylbenzene1carboximidamide
_version_ 1725103380598095872

Similar Items