4-Methyl-N′-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide
The title compound, C10H10Cl3N3, features a delocalized unsaturated N...;C...;N...;C...;N chain and strong intramolecular N—H...N hydrogen bonding across the chelate ring and also intramolecular N—H...Cl contacts to a CCl3-group Cl atom. The only intermolecular contacts i...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811044710 |
| Summary: | The title compound, C10H10Cl3N3, features a delocalized unsaturated N...;C...;N...;C...;N chain and strong intramolecular N—H...N hydrogen bonding across the chelate ring and also intramolecular N—H...Cl contacts to a CCl3-group Cl atom. The only intermolecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl3 groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N—C bond between the carboximidamide and imine components [C—N—C—N torsion angle = −23.6 (2) °]. |
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| ISSN: | 1600-5368 |