Unexpected reactions of NHC*—CuI and —AgI bromides with potassium thio- or selenocyanate

Unexpected reactions of NHC*—CuI and —AgI bromides with potassium thio- or selenocyanate

The reactions of N-heterocyclic carbene CuI and AgI halides with potassium thio- or selenocyanate gave unexpected products. The attempted substitution reaction of bromido(1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene)silver (NHC*—Ag—Br) with KSCN yielded bis[bis(1,3-dibenzyl-4,5-diphenylimidazol-2-yli...

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Bibliographic Details
Main Authors: Matthias Tacke, Daniel Marhöfer, Hessah Althani, Helge Müller-Bunz
Format: Article
Language:English
Published: International Union of Crystallography 2019-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
n-heterocyclic carbene
copper(i)
silver(i)
thiocyanate
selenocyanate
d10 electron configuration
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019013719

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http://scripts.iucr.org/cgi-bin/paper?S2056989019013719

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