Active and stable platinum/ionic liquid/carbon nanotube electrocatalysts for oxidation of methanol

• Main Authors: Guan-Lin Lin, Arun Prakash Periasamy, Zih-Yu Shih, Huan-Tsung Chang
• Format: Article
• Language: English
• Published: ScienceOpen 2014-10-01
• Series: ScienceOpen Research
• Subjects: Platinum nanoparticles; Carbon nanotubes; Methanol oxidation reaction; Anode cataly; Imidazolium ionic liquids
• Online Access: https://www.scienceopen.com/document/vid/5d304b97-4244-4235-8cf7-546b348dd9fd?11

Platinum (Pt) nanoparticles (NPs) on carbon nanotubes (CNTs) from PtCl62− ions through a facile ionic liquid (IL)-assisted method has been developed and used for methanol oxidation. 1-Butyl-3-methylimidazolium (BMIM) with four different counter ions (PF6−, Cl–, Br–, and I–) have been tested for the preparation of Pt/IL/CNT nanohybrids, showing the counterions of ILs play an important role in the formation of small sizes of Pt NPs. Only [BMIM][PF6] and [BMIM][Cl] allow reproducible preparation of Pt/IL/CNT nanohybrids. The electroactive surface areas of Pt/[BMIM][PF6]/CNT, Pt/[BMIM][Cl]/CNT, Pt/CNT, and commercial Pt/C electrodes are 62.8, 101.5, 78.3, and 87.4 m2 g−1, respectively. The Pt/[BMIM][Cl]/CNT nanohybrid-modified electrodes provide higher catalytic activity (251.0 A g−1) at a negative onset potential of −0.60 V than commercial Pt/C-modified ones do (133.5 A g−1) at −0.46 V. The Pt/[BMIM][Cl]/CNT electrode provides the highest ratio (4.52) of forward/reverse oxidation current peak, revealing a little accumulation of carbonaceous residues.