| Summary: | Tridimensional cubic mesoporous silica, SBA-16, functionalized with aminopropyl groups, were employed as adsorbents for Pb<sup>2+</sup> ion removal from aqueous solution. The adsorption capacity was investigated for the effect of pH, contact time, temperature, and concentration of 3-aminopropyltriethoxysilane (APTES) employed for adsorbent functionalization. The textural properties and morphology of the adsorbents were evaluated by N<sub>2</sub> physisorption, small-angle X-ray diffraction (XRD), diffuse reflectance spectroscopy (UV-vis), and transmission electron microscopy (TEM). The functionalization of the SBA-16 was evaluated by elemental analysis (N), thermogravimetric analysis (TG), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). Batch adsorption studies show that the total Pb<sup>2+</sup> ions removal was archived on adsorbent having an optimized amount of aminopropyl groups (2N-SBA-16). The maximum of Pb<sup>2+</sup> ions removal occurred at optimized adsorption conditions: pH = 5−6, contact time 40 min, and at a low initial lead concentration in solution (200 mg L<sup>−1</sup>). Under the same adsorption conditions, the amino-functionalized SBA-16 with cubic 3D unit cell structure exhibited higher adsorption capability than its SBA-15 counterpart with uniform mesoporous channels.
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