A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction
[Cu(CPA)(BDC)]<sub>n</sub> (CPA = 4-(Chloro-phenyl)-pyridin-4-ylmethylene-amine; BDC = 1,4-benzenedicarboxylate) has been synthesized and structurally characterized by single crystal X-Ray diffraction measurement. The structural studies establish the copper (II) containing 2D sheet with...
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MDPI AG
2021-08-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/26/17/5296 |
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doaj-99fc2b57faa54125a41fe02108b40b282021-09-09T13:53:26ZengMDPI AGMolecules1420-30492021-08-01265296529610.3390/molecules26175296A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel ReactionKaushik Naskar0Suvendu Maity1Himadri Sekhar Maity2Chittaranjan Sinha3Department of Chemistry, Jadavpur University, Kolkata 700032, IndiaDepartment of Chemistry, Jadavpur University, Kolkata 700032, IndiaDepartment of Chemistry, Indian Institute of Technology, Kharagpur 721302, IndiaDepartment of Chemistry, Jadavpur University, Kolkata 700032, India[Cu(CPA)(BDC)]<sub>n</sub> (CPA = 4-(Chloro-phenyl)-pyridin-4-ylmethylene-amine; BDC = 1,4-benzenedicarboxylate) has been synthesized and structurally characterized by single crystal X-Ray diffraction measurement. The structural studies establish the copper (II) containing 2D sheet with (4,4) square grid structure. The square grid lengths are 10.775 and 10.769 Å. Thermal stability is assessed by TGA, and subsequent PXRD data establish the crystallinity. The surface morphology is evaluated by FE-SEM. The N<sub>2</sub> adsorption−desorption analysis demonstrates the mesoporous feature (∼6.95 nm) of the Cu-MOF. This porous grid serves as heterogeneous green catalyst with superficial recyclability and thermal stability and facilitates organic transformations efficiently such as, Click and Knoevenagel reactions in the aqueous methanolic medium.https://www.mdpi.com/1420-3049/26/17/52962D Cu-MOFsquare grid structureClick reactionKnoevenagel reactiongreen chemistry |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Kaushik Naskar Suvendu Maity Himadri Sekhar Maity Chittaranjan Sinha |
| spellingShingle |
Kaushik Naskar Suvendu Maity Himadri Sekhar Maity Chittaranjan Sinha A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction Molecules 2D Cu-MOF square grid structure Click reaction Knoevenagel reaction green chemistry |
| author_facet |
Kaushik Naskar Suvendu Maity Himadri Sekhar Maity Chittaranjan Sinha |
| author_sort |
Kaushik Naskar |
| title |
A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction |
| title_short |
A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction |
| title_full |
A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction |
| title_fullStr |
A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction |
| title_full_unstemmed |
A Reusable Efficient Green Catalyst of 2D Cu-MOF for the Click and Knoevenagel Reaction |
| title_sort |
reusable efficient green catalyst of 2d cu-mof for the click and knoevenagel reaction |
| publisher |
MDPI AG |
| series |
Molecules |
| issn |
1420-3049 |
| publishDate |
2021-08-01 |
| description |
[Cu(CPA)(BDC)]<sub>n</sub> (CPA = 4-(Chloro-phenyl)-pyridin-4-ylmethylene-amine; BDC = 1,4-benzenedicarboxylate) has been synthesized and structurally characterized by single crystal X-Ray diffraction measurement. The structural studies establish the copper (II) containing 2D sheet with (4,4) square grid structure. The square grid lengths are 10.775 and 10.769 Å. Thermal stability is assessed by TGA, and subsequent PXRD data establish the crystallinity. The surface morphology is evaluated by FE-SEM. The N<sub>2</sub> adsorption−desorption analysis demonstrates the mesoporous feature (∼6.95 nm) of the Cu-MOF. This porous grid serves as heterogeneous green catalyst with superficial recyclability and thermal stability and facilitates organic transformations efficiently such as, Click and Knoevenagel reactions in the aqueous methanolic medium. |
| topic |
2D Cu-MOF square grid structure Click reaction Knoevenagel reaction green chemistry |
| url |
https://www.mdpi.com/1420-3049/26/17/5296 |
| work_keys_str_mv |
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