syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate

syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate

The title compound, C30H18Cl6O3·0.82CH2Cl2, consists of a slightly cup-shaped seven-ring truxene nucleus with hydroxy and dichloromethyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C—Cl distances are in the range 1.759 (4)–1.783&amp...

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Main Authors: Gregory W. Morrison, Frank R. Fronczek, Steven F. Watkins
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812020703
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spelling doaj-995c6e06b2d6483587475bf9df4e53142020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1755o175610.1107/S1600536812020703syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvateGregory W. MorrisonFrank R. FronczekSteven F. WatkinsThe title compound, C30H18Cl6O3·0.82CH2Cl2, consists of a slightly cup-shaped seven-ring truxene nucleus with hydroxy and dichloromethyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C—Cl distances are in the range 1.759 (4)–1.783 (3) Å. Solvent channels parallel to the b axis appear to be partially occupied by highly disordered dichloromethane solvent molecules, the contribution of which were removed from the refinement with the SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. Only one of the OH groups forms a hydrogen bond, which is intermolecular to another OH group, forming centrosymmetric dimers in the crystal.http://scripts.iucr.org/cgi-bin/paper?S1600536812020703
collection DOAJ
language English
format Article
sources DOAJ
author Gregory W. Morrison
Frank R. Fronczek
Steven F. Watkins
spellingShingle Gregory W. Morrison
Frank R. Fronczek
Steven F. Watkins
syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
Acta Crystallographica Section E
author_facet Gregory W. Morrison
Frank R. Fronczek
Steven F. Watkins
author_sort Gregory W. Morrison
title syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
title_short syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
title_full syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
title_fullStr syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
title_full_unstemmed syn-5,10,15-Tris(dichloromethyl)-5,10,15-trihydroxy-5H-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
title_sort syn-5,10,15-tris(dichloromethyl)-5,10,15-trihydroxy-5h-diindeno[1,2-a:1′,2′-c]fluorene dichloromethane 0.82-solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description The title compound, C30H18Cl6O3·0.82CH2Cl2, consists of a slightly cup-shaped seven-ring truxene nucleus with hydroxy and dichloromethyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C—Cl distances are in the range 1.759 (4)–1.783 (3) Å. Solvent channels parallel to the b axis appear to be partially occupied by highly disordered dichloromethane solvent molecules, the contribution of which were removed from the refinement with the SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. Only one of the OH groups forms a hydrogen bond, which is intermolecular to another OH group, forming centrosymmetric dimers in the crystal.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812020703
work_keys_str_mv AT gregorywmorrison syn51015trisdichloromethyl51015trihydroxy5hdiindeno12a1amp82422amp8242cfluorenedichloromethane082solvate
AT frankrfronczek syn51015trisdichloromethyl51015trihydroxy5hdiindeno12a1amp82422amp8242cfluorenedichloromethane082solvate
AT stevenfwatkins syn51015trisdichloromethyl51015trihydroxy5hdiindeno12a1amp82422amp8242cfluorenedichloromethane082solvate
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