Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3

The heat of fusion of eutectic mixtures of sodium cryolite with alumina and calcium fluoride was measured using differential scanning calorimetry. Melting temperatures were found to be in good agreement with literature data. The molar heat of fusion of cryolite salts and eutectic mixtures was found...

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Main Authors: Alexander A. Redkin, Svetlana V. Pershina, Evgenia A. Il'ina, Alexander A. Kataev, Yurii P. Zaikov
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2019-10-01
Series:Chimica Techno Acta
Subjects:
Online Access:https://journals.urfu.ru/index.php/chimtech/article/view/3986
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spelling doaj-98d3028f3c204b518920194ddbf325502020-11-25T01:54:26ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina Chimica Techno Acta2409-56132411-14142019-10-016310411010.15826/chimtech.2019.6.3.033300Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3Alexander A. Redkin0Svetlana V. Pershina1Evgenia A. Il'ina2Alexander A. Kataev3Yurii P. Zaikov4Institute of High-Temperature Electrochemistry UB RAS, EkaterinburgInstitute of High-Temperature Electrochemistry UB RAS, EkaterinburgInstitute of High-Temperature Electrochemistry UB RAS, EkaterinburgInstitute of High-Temperature Electrochemistry UB RAS, EkaterinburgInstitute of High-Temperature Electrochemistry UB RAS; Ural Federal University, EkaterinburgThe heat of fusion of eutectic mixtures of sodium cryolite with alumina and calcium fluoride was measured using differential scanning calorimetry. Melting temperatures were found to be in good agreement with literature data. The molar heat of fusion of cryolite salts and eutectic mixtures was found to be directly dependent on melting temperature. The temperature dependence coefficient is the same as that of alkali halides.https://journals.urfu.ru/index.php/chimtech/article/view/3986heat of fusionmelting pointcryoliteheat balancedifferential scanning calorimetry
collection DOAJ
language English
format Article
sources DOAJ
author Alexander A. Redkin
Svetlana V. Pershina
Evgenia A. Il'ina
Alexander A. Kataev
Yurii P. Zaikov
spellingShingle Alexander A. Redkin
Svetlana V. Pershina
Evgenia A. Il'ina
Alexander A. Kataev
Yurii P. Zaikov
Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3
Chimica Techno Acta
heat of fusion
melting point
cryolite
heat balance
differential scanning calorimetry
author_facet Alexander A. Redkin
Svetlana V. Pershina
Evgenia A. Il'ina
Alexander A. Kataev
Yurii P. Zaikov
author_sort Alexander A. Redkin
title Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3
title_short Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3
title_full Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3
title_fullStr Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3
title_full_unstemmed Heat of Fusion of Na3AlF6 Eutectic Mixtures with CaF2 and Al2O3
title_sort heat of fusion of na3alf6 eutectic mixtures with caf2 and al2o3
publisher Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
series Chimica Techno Acta
issn 2409-5613
2411-1414
publishDate 2019-10-01
description The heat of fusion of eutectic mixtures of sodium cryolite with alumina and calcium fluoride was measured using differential scanning calorimetry. Melting temperatures were found to be in good agreement with literature data. The molar heat of fusion of cryolite salts and eutectic mixtures was found to be directly dependent on melting temperature. The temperature dependence coefficient is the same as that of alkali halides.
topic heat of fusion
melting point
cryolite
heat balance
differential scanning calorimetry
url https://journals.urfu.ru/index.php/chimtech/article/view/3986
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