Characterization of aerosol hygroscopicity using Raman lidar measurements at the EARLINET station of Payerne

• Main Authors: F. Navas-Guzmán, G. Martucci, M. Collaud Coen, M. J. Granados-Muñoz, M. Hervo, M. Sicard, A. Haefele
• Format: Article
• Language: English
• Published: Copernicus Publications 2019-09-01
• Series: Atmospheric Chemistry and Physics
• Online Access: https://www.atmos-chem-phys.net/19/11651/2019/acp-19-11651-2019.pdf

<p>This study focuses on the analysis of aerosol hygroscopicity using remote sensing techniques. Continuous observations of aerosol backscatter coefficient (<span class="inline-formula"><i>β</i>^aer</span>), temperature (<span class="inline-formula"><i>T</i></span>) and water vapor mixing ratio (<span class="inline-formula"><i>r</i></span>) have been performed by means of a Raman lidar system at the aerological station of MeteoSwiss at Payerne (Switzerland) since 2008. These measurements allow us to monitor in a continuous way any change in aerosol properties as a function of the relative humidity (RH). These changes can be observed either in time at a constant altitude or in altitude at a constant time. The accuracy and precision of RH measurements from the lidar have been evaluated using the radiosonde (RS) technique as a reference. A total of 172 RS profiles were used in this intercomparison, which revealed a bias smaller than 4&thinsp;%&thinsp;RH and a standard deviation smaller than 10&thinsp;%&thinsp;RH between both techniques in the whole (in lower) troposphere at nighttime (at daytime), indicating the good performance of the lidar for characterizing RH. A methodology to identify situations favorable to studying aerosol hygroscopicity has been established, and the aerosol hygroscopicity has been characterized by means of the backscatter enhancement factor (<span class="inline-formula"><i>f</i>_<i>β</i></span>). Two case studies, corresponding to different types of aerosol, are used to illustrate the potential of this methodology.</p> <p>The first case corresponds to a mixture of rural aerosol and smoke particles (smoke mixture), which showed a higher hygroscopicity (<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M5" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi>f</mi><mi mathvariant="italic">β</mi><mn mathvariant="normal">355</mn></msubsup><mo>=</mo><mn mathvariant="normal">2.8</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="49pt" height="18pt" class="svg-formula" dspmath="mathimg" md5hash="008c8c56d3437edf710ca649089133e5"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-11651-2019-ie00001.svg" width="49pt" height="18pt" src="acp-19-11651-2019-ie00001.png"/></svg:svg></span></span> and <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M6" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi>f</mi><mi mathvariant="italic">β</mi><mn mathvariant="normal">1064</mn></msubsup><mo>=</mo><mn mathvariant="normal">1.8</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="53pt" height="18pt" class="svg-formula" dspmath="mathimg" md5hash="69cdb07d75295f6b4f0ed35e3132ccbf"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-11651-2019-ie00002.svg" width="53pt" height="18pt" src="acp-19-11651-2019-ie00002.png"/></svg:svg></span></span> in the RH range 73&thinsp;%–97&thinsp;%) than the second case, in which mineral dust was present (<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M7" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi>f</mi><mi mathvariant="italic">β</mi><mn mathvariant="normal">355</mn></msubsup><mo>=</mo><mn mathvariant="normal">1.2</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="49pt" height="18pt" class="svg-formula" dspmath="mathimg" md5hash="59b1adb84690727f0d4b37ad02460b89"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-11651-2019-ie00003.svg" width="49pt" height="18pt" src="acp-19-11651-2019-ie00003.png"/></svg:svg></span></span> and <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M8" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi>f</mi><mi mathvariant="italic">β</mi><mn mathvariant="normal">1064</mn></msubsup><mo>=</mo><mn mathvariant="normal">1.1</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="53pt" height="18pt" class="svg-formula" dspmath="mathimg" md5hash="e90553b976d5694e776994276bd8e8a9"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-11651-2019-ie00004.svg" width="53pt" height="18pt" src="acp-19-11651-2019-ie00004.png"/></svg:svg></span></span> in the RH range 68&thinsp;%–84&thinsp;%).</p> <p>The higher sensitivity of the shortest wavelength to hygroscopic growth was qualitatively reproduced using Mie simulations. In addition, a good agreement was found between the hygroscopic analysis done in the vertical and in time for Case I, where the latter also allowed us to observe the hydration and dehydration of the smoke mixture. Finally, the impact of aerosol hygroscopicity on the Earth's radiative balance has been evaluated using the GAME (Global Atmospheric Model) radiative transfer model. The model showed an impact with an increase in absolute value of 2.4&thinsp;W&thinsp;m<span class="inline-formula">⁻²</span> at the surface with respect to the dry conditions for the hygroscopic layer of Case I (smoke mixture).</p>